Studies on the Proton Magnetic Resonance Spectra of Aromatic Systems. XXI. Discussions on Stoichiometry, Equilibrium and Infinite Concentration Shift of Pyridine Base-Tris (dipivalometh-anato) europium Eu (DPM)_3 Complex in Solution

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概要

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• The 1 : 1 complex formations between pyridine bases and Eu (DPM)_3 are approved at equimolar, excess base and excess Eu (DPM)_3 conditions. The equilibrium constants and complex shifts are estimated by the graphic and simulation methods of the observed results of the above three conditions. The complex shifts thus obtained showed good correspondence with infinite concent-ration shifts and the so-called S values. The equilibrium constants are solvent dependent, whereas the complex shifts are not.

• 社団法人日本薬学会の論文
• 1977-12-25

著者

• 岡崎 雄交

  Faculty of Pharmaceutical Sciences, Kinki University

• 藤原 英明

  大阪大 医

• 藤原 英明

  Faculty Of Pharmaceutical Sciences Osaka University

• 佐々木 喜男

  Faculty of Pharmaceutical Sciences, Osaka University

• 佐々木 喜男

  Faculty Of Pharmaceutical Sciences Osaka University

• 岡崎 雄交

  近畿大 薬

• 岡崎 雄交

  Faculty Of Pharmaceutical Sciences Kinki University

• 川木 秀子

  近畿大 薬学総研

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