Studies on the Proton Magnetic Resonance Spectra of Aliphatic Systems. VIII. Complex Shift and Equilibrium Constant of Aliphatic Alcohol-Tris (dipivalomethanato) europium Complex in Solution
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概要
- 論文の詳細を見る
1 : 1 Complex formation between Eu (DPM)_3 and aliphatic alcohol was confirmed under the condition of [Eu (DPM)_3] ≳ [ROH] in a dilute solution, where the concentrations of donor [ROH] and acceptor [Eu (DPM)_3] are below 0.02M, respectively. Of the two parameters K_c and Δ_c estimated by the computer simulation of the equilibrium equation, the formers are solvent dependent, whereas the latters are not. Δ_<AD> and ΔG estimated from the solute-solvent interaction model are comparable with the 1 : 1 complex shift Δ_c and free energy obtained from the temperature dependence of K_c, and the infinite concentration shifts Δ_<ic> are also comparable with Δ_c.
- 社団法人日本薬学会の論文
- 1978-04-25
著者
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岡崎 雄交
Faculty of Pharmaceutical Sciences, Kinki University
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藤原 英明
大阪大 医
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藤原 英明
Faculty Of Pharmaceutical Sciences Osaka University
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佐々木 喜男
Faculty of Pharmaceutical Sciences, Osaka University
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佐々木 喜男
Faculty Of Pharmaceutical Sciences Osaka University
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岡崎 雄交
近畿大 薬
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岡崎 雄交
Faculty Of Pharmaceutical Sciences Kinki University
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川木 秀子
近畿大 薬学総研
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