Studies on the Proton Magnetic Resonance Spectra in Aliphatic Systems. V. Tris (dipivalomethanato) europium Induced Shift Parameters of Aliphatic Amines and Alcohols
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概要
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The induced paramagnetic shift parameters, S values, of simple aliphatic amines and alcohols, and the α-substituted propane and β-substituted ethanol series were measured at a mole ratio of Eu (DPM)_3/ligand in CDCl_3 of below 0.10. The S value is a measure of the equilibrium between the shift reagent and ligand, for which the steric and electronic effects are responsible, and is expressed by the equation, S=A. e-BΔE where ΔE=ΔE_<elect>+ΔE_<steric>
- 公益社団法人日本薬学会の論文
- 1973-11-25
著者
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岡崎 雄交
Faculty of Pharmaceutical Sciences, Kinki University
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佐々木 喜男
Faculty of Pharmaceutical Sciences, Osaka University
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佐々木 喜男
Faculty Of Pharmaceutical Sciences Osaka University
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岡崎 雄交
近畿大 薬
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岡崎 雄交
Faculty Of Pharmaceutical Sciences Kinki University
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川木 秀子
近畿大 薬学総研
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