Studies on the Proton Magnetic Resonance Spectra in Aromatic Systems. XVIII. Tris (dipivalomethanato) europium Induced Shift of para- and meta-Substituted Deuteroanilines
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概要
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The S values, those are the paramagnetic shift parameters of deuterated and undeuterated and undeuterated para- and meta-substituted aniline derivatives induced by tris (dipivalomethanato) europium, were measured. The observed S values of compounds in the para-substituted series were linearly related with the substituent constants σ_π, whereas those of the meta-substituted series were linearly related with σ_i. The following results were obtained for the magnitudes, S_h and S_d, and the slopes, ρ_h and ρ_d, of the undeuterated and deuterated compounds in the two series : S_d>S_h and ρ_d/ρ_h=1.35.
- 公益社団法人日本薬学会の論文
- 1974-01-25
著者
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岡崎 雄交
Faculty of Pharmaceutical Sciences, Kinki University
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佐々木 喜男
Faculty Of Pharmaceutical Sciences Osaka University
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岡崎 雄交
近畿大 薬
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岡崎 雄交
Faculty Of Pharmaceutical Sciences Kinki University
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川木 秀子
近畿大 薬学総研
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寄高 みち子
Faculty of Pharmaceutical Sciences, Osaka University
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寄高 みち子
Faculty Of Pharmaceutical Sciences Osaka University
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