A Method to Identify the Absolute Configuration of Rhamnose, Lyxose, and 2,6-Dideoxy Sugars, Cymarose, Oleandrose, Diginose, and Digitoxose, Using a Chiral High-Performance Liquid Chromatography (HPLC) Column
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概要
- 論文の詳細を見る
D-Diginose and L-diginose (2,6-dideoxy-3-O-methyl-lyxo-hexose) have been separated as the carbamoyl derivatives of the methyl glycosides by higy-performance liquid chromatography (HPLC) using a chiral column (SUMIPAX OA-4100).In the cases of other 2,6-dideoxyhexoses, cymarose, oleandrose, and digitoxose, this column was more suitable for the enantiomeric separation than the column previously used (SUMIPAX OA-1000).The enantiomeric mixtures of cymarose obtained from Cynanchum wilfordi glycosides were analyzed by using the SUMIPAX OA-4100 column.Further, the enantiomers of rhamnose and lyxose have been separated as the carbamoyl derivatives of the acetonides by means of the chiral column.
- 公益社団法人日本薬学会の論文
- 1989-03-25
著者
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林 紘司
Faculty of Pharmaceutical Sciences, Hokkaido University
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林 紘司
Tsumura Central Research Laboratories Tsumura & Co.
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金子 光
Faculty of Pharmaceutical Sciences, Hokkaido University
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塚本 佐知子
Faculty of Pharmaceutical Sciences, Hokkaido University
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金子 光
Faculty Of Pharmaceutical Sciences Hokkaido University
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塚本 佐知子
Faculty Of Pharmaceutical Sciences Hokkaido University
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金子 光
北海道大学 薬
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林 紘司
Faculty Of Pharmaceutical Sciences Hokkaido University
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林 紘司
北海道大学薬学部
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