Studies on the Constituents of Umbelliferae Plants. XVI. Isolation and Structures of Three New Ligustilide Derivatives from Angelica acutiloba(Organic,Chemical)

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概要

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• Three new ligustilide derivatives (3-5) were isolated from the crude drug toki, the dried roots of the Umbelliferae plant Angelica acutiloba, together with a known ligustilide dimer, levistolide A (2), and four known oxygenated ligustilide derivatives, senkyunolide E (6), senkyunolide F (7), senkyunolide H (8) and senkyunolide I (9). Compound 3 was shown to be the angeloyl ester of 7. Compounds 4 and 5, designated tokinolide A and tokinolide B, are dimeric ligustilide derivatives with. Diels-Alder-type (5) and cyclobutane-type (4) cyclization systems, respectively. The occurrence of compounds 2 to 9 in a fresh A. acutiloba sample was confirmed.

• 公益社団法人日本薬学会の論文
• 1987-11-25

著者

• 小林 優

  Faculty Of Pharmaceutical Sciencces Hokkaido University

• 小林 優

  北大薬

• 土田 貴志

  Faculty of Pharmaceutical Sciences, Hokkaido University

• 金子 光

  Faculty of Pharmaceutical Sciences, Hokkaido University

• 三橘 博

  Faculty of Pharmaceutical Sciences, Hokkaido University

• 金子 光

  Faculty Of Pharmaceutical Sciences Hokkaido University

• 土田 貴志

  Faculty Of Pharmaceutical Sciences Hokkaido University

• 三橘 博

  Faculty Of Pharmaceutical Sciences Hokkaido University

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