Reaction of Some Steroidal Amides and Unsaturated Lactams with Nitrous Acid
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概要
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The reaction of nitrous acid with steroidal amides (I, VII, IX and X), α, β-unsturated ε-lactams (XIX and XXI), and enamine-type lactams (XXIV, XXVIII, XXX and XXXI) was studied. The amides mainly gave esters in low or modest yield with retention of the configuration. The α, β-unsaturated lactams gave N-nitroso-lactams quantitatively. The enamine-type δ-lactams gave oximino-δ-lactams in a high yield.
- 公益社団法人日本薬学会の論文
- 1973-05-25
著者
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三橋 博
Faculty of Pharmaceutical Sciences, Hokkaido University
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三橋 博
Tsumura Institute For Biology And Chemistry
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三橋 博
Faculty Of Pharmaceutical Sciences Hokkaido University
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小林 優
Faculty Of Pharmaceutical Sciencces Hokkaido University
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