Studies on the Structure of Itaconitin. IV. The Reactions of Itaconitin and Anhydroitaconitin
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概要
- 論文の詳細を見る
The ozonolysis of anhydroitaconitin which was prepared from itaconitin by the action of acetic or propionic anhydride followed by hydrolysis, yielded, 2,4-cresotaldehyde liberating acetaldehyde and carbon dioxide. Treatment of the same substance with nitric acid afforded 2,4,6-trinitro-m-cresol. These and other experimental results showed that the anhydroitaconitin was an aromatic compound having a m-cresyl grouping with an adjacent ethylenic linkage. The catalytic hydrogenation of anhydroitaconitin in acetone gave dihydroanhydroitaconitin, whereas in alkali gave a carboxylic acid, C_<14>H_<18>O_5.
- 公益社団法人日本薬学会の論文
- 1965-01-25
著者
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柴田 承二
Faculty of Pharmaceutical Sciences, University of Tokyo
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仲嶋 正一
Faculty of Pharmaceutical Sciences, Hoshi University
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木下 広野
Hoshi College Of Pharmacy
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柴田 承二
Faculty Of Pharmaceutical Sciences University Of Tokyo:(present Address)meiji College Of Pharmacy
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仲嶋 正一
Hoshi College of Pharmacy
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柴田 承二
Faculty Of Pharmaceutical Sciences University Of Tokyo
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仲嶋 正一
Faculty Of Pharmaceutical Sciences Hoshi University
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