Biocatalytic Production of Chiral Epichlorohydrin in Organic Solvents
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概要
- 論文の詳細を見る
Enantioselective hydrolysis of racemic epichlorohydrin was accomplished for the production of enantiopure epichlorohydrin using the whole cells of an isolated Aspergillus niger spps. To overcome the spontaneous chemical degradation of epichlorohydrin that occurs in aqueous buffer, organic solvents were employed in the reaction medium. The enantioselectivity was highly dependent on the solvent structure, water content of the medium, and the initial epichlorohydrin concentration. (S)-Epichlorohydrin could be obtained from its racemates (60 mM) with an optical purity of 100% enantiomeric excess (ee) and 20% yield in cyclohexane supplemented with 2.0% (v/v) water.
- 社団法人日本生物工学会の論文
- 1999-09-25
著者
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LEE Eun
Department of Anesthesiology and Pain Medicine, Asan Medical Center, University of Ulsan College of
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Yoon Sung
Department of Cardiology, School of Medicine, Keio University
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Choi Won
Department Of Physiology And Anesthesiology College Of Medicine Institute Of Biomedical Science And
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Yoon Sung
Department Of Biotechnology Dongseo University
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CHOI CHA
Department of Chemical Technology, College of Engineering, Seoul National University
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Choi Won
Department Of Agricultural Chemistry Kyushu University
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Choi Cha
Department Of Chemical Technology College Of Engineeering Seoul National University
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YANG SEUNG-TAEK
Department of Food Science and Technology, College of Engineering, Kyungsung University
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Lee Eun
Department Of Food Science And Technology College Of Engineering Kyungsung University
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Yang Seung-taek
Department Of Food Science And Technology College Of Engineering Kyungsung University
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Yoon Sung
Department Of Food Science And Technology College Of Engineering Kyungsung University
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Choi Won
Department Of Chemical Technology College Of Engineering Seoul National University
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Lee Eun
Department Of Anesthesiology And Pain Medicine Asan Medical Center University Of Ulsan College Of Me
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