Identification of 2,3-Dihydro-γ-ionylideneethanol in Cercospora cruenta
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概要
- 論文の詳細を見る
During our scrutiny of GC-EI-MS date for C_<15> alcohols as putative intermediates on the ABA biosynthetic pathway in Cercospora cruenta, a trace amount of 5-[2', 2'-dimethyl-6'-methylene-1'-cyclohexyl]-3-methyl-4-penten-1-ol (2,3-dihydro-γ-ionylideneethanol) was identified. Feeding experiments indicated that this compound was not an intermediate to ABA, but a catabolite that originated from γ-ionylideneacetaldehyde. The stereochemistry of 2,3-dihydro-γ-ionylideneethanol was deduced to be (3R, 1'S) from a comparison with an authentic specimen prepared via baker's yeast asymmetric reduction.
- 社団法人日本農芸化学会の論文
- 2001-04-23
著者
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Yamamoto H
Life Science Development Center Cpi Company Daicel Chemical Industries Ltd. Tsukuba Research Center
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Inomata Masahiro
Faculty Of Agriculture Niigata University
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Yamamoto Hiroaki
Life Science Development Center Cpi Company Daicel Chemical Industries Ltd. Tsukuba Research Center
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Uchiyama T
Department Of Applied Biological Chemistry Faculty Of Agriculture Niigata University
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Uchiyama Takeo
Faculty Of Agriculture Niigata University
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YAMAMOTO Hirotaka
Faculty of Agriculture, Niigata University
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ORITANI Takayuki
Graduate School of Agricultural Science, Tohoku University
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Yamashita H
Mathematical Systems Inc.
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Uchiyama T
Faculty Of Agriculture Niigata University
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Oritani T
Laboratory Of Applied Bioorganic Chemistry Division Of Bioscience & Biotechnology For Future Bio
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Yamamoto Hirotaka
Faculty Of Agriculture Niigata University
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