Isolation and Structural Determination of a Novel Bicyclic Taxane Diterpene from Needles of the Chinese Yew, Taxus mairei

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概要

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• A novel bicyclic taxane diterpene with a rare 12-mem-bered ring was isolated from needles of the Chinese yew, Taxus mairei, and its structure was established as (3E, 8E)-2α, 7β, 9,10β, 13α, 20-hexaacetoxy-5 (2'-acetoxy-cinnamoyloxy)-3,8-secotaxa-3,8,11-triene (1) with the help of 1D and 2D NMR data. The relative stereochemistry was deduced from a NOESY experiment.

• 社団法人日本農芸化学会の論文
• 1999-04-23

著者

• ORITANI Takayuki

  Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultura

• 杉山 長美

  Tohoku Univ. Sendai Jpn

• Shi Q‐w

  Department Of Natural Product Chemistry School Of Pharmaceutical Sciences Hebei Medicinal University

• SUGIYAMA Takeyoshi

  Laboratory of Applied Bioorganic Chemistry, Graduate School of Agricultural Science, Tohoku Universi

• SHI QingWen

  Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultura

• YAMADA Teiko

  Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultura

• Shi Qingwen

  Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural

• Yamada Teiko

  Laboratory Of Applied Bioorganic Chemistry Division Of Bioscience & Biotechnology For Future Bio

• Yamada Takao

  Department Of Agricultural Chemistry Faculty Of Agriculture Niigata University

• Sugiyama Takeyoshi

  Laboratory Of Applied Bioorganic Chemistry Graduate School Of Agricultural Science Tohoku University

• Yamada T

  Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural

• Oritani T

  Laboratory Of Applied Bioorganic Chemistry Division Of Bioscience & Biotechnology For Future Bio

• Oritani Takayuki

  Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural

• Shi Q‐w

  Laboratory Of Applied Bioorganic Chemistry Graduate School Of Agricultural Science Tohoku University

• Shi Qing-wen

  Department Of Natural Product Chemistry School Of Pharmaceutical Sciences Hebei Medicinal University

• Shi Qing-wen

  Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural

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