Enzymatic Resolution of (±)-Epoxy-β-cyclogeraniol, a Synthetic Precursor for Abscisic Acid Analogs
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概要
- 論文の詳細を見る
Lipase-catalyzed optical resolution of (±)-epoxy-β-cyclogeraniol (1) a key synthetic intermediate for epoxy-β-ionylideneacetic acid, was achieved in high enantiomeric purity. Transesterification with vinyl acetate by using lipase P (Nagase) made enriched (-)-1,while hydrolysis of the corresponding acetate by using lipase P (Amano) afforded (+)-1 with a high E value (E=1600).
- 社団法人日本農芸化学会の論文
- 2000-07-23
著者
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Kiyota Hiromasa
Laboratory Of Applied Bioorganic Chemistry Division Of Bioscience & Biotechnology For Future Bio
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Oritani Takayuki
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
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OKAZAKI Ryou
Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultura
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Okazaki R
Tohoku Univ. Sendai Jpn
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Okazaki Ryou
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
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Kiyota Hiromasa
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
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Oritani Takayuki
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
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