Synthesis of (-)-Methyl Shikimate via Enzymatic Resolution of (1S^*, 4R^*, 5R^*)-4-Hydroxy-6-oxabicyclo [3.2.1] oct-2-en-7-one(Organic Chemistry)
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概要
- 論文の詳細を見る
The synthesis of methyl (-)-shikimate [(-)-2] was achieved via lipase-catalyzed optical resolution of (1S^*, 4R^*, 5R^*)-4-hydroxy-6-oxabicyclo [3.2.1] oct-2-en-7-one (3). Transesterification of (±)-3 and vinyl acetate with lipase MY and subsequent hydrolysis gave optically pure (-)-3. This compound was converted to (-)-2 in two steps.
- 社団法人日本農芸化学会の論文
- 2001-09-23
著者
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Kiyota Hiromasa
Laboratory Of Applied Bioorganic Chemistry Division Of Bioscience & Biotechnology For Future Bio
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Oritani Takayuki
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
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UEDA Rumi
Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultura
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Ueda Rumi
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
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Kiyota Hiromasa
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
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Oritani Takayuki
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
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