Microbial Hydroxylation of (±)- and(-)-(2Z, 4E)-5-(1', 2'-Epoxy-2', 6', 6'-trimethylcyclohexyl)-3-methyl-2,4-pentadienoic acid into (±)-and (-)-Xanthoxin Acid by Cunninghamella echinulata
スポンサーリンク
概要
- 論文の詳細を見る
Microbial hydroxylation of (±)-(2Z, 4E)-5-(1', 2'-epoxy-2', 6', 6'-trimethylcyclohexyl)-3-methyl-2,4-pentadienoic acid (3a) with Cercospora cruenta, a fungus producing (+)-abscisic acid, gave a four-stereolsomeric mixture consisting of (+)-and(-)-xanthoxin acid (4a), and (+)-and (-)-epi-xanthoxin acid (5a) by an HPLC analysis with a chiral column. Screening of the microorganisms capable of oxidizing (±)-3a showed that Cunninghamella echinulata stereoselectively oxidized (±)-3a to xanthoxin acid (4a) with the some degree of enantioselectivity as (-)-3a to (-)-4a.
- 社団法人日本農芸化学会の論文
- 2001-04-23
著者
-
YAMAMOTO HIROTAKA
Department of Pharmaceutical Sciences, Tohoku University Hospital
-
Oritani Takayuki
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
-
Okazaki Ryou
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
-
HARA Yoshihiro
Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultura
-
Oritani Takayuki
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
-
Hara Yoshihiro
Laboratory Of Applied Bioorganic Chemistry Division Of Life Science Graduate School Of Agricultural
-
Yamamoto Hirotaka
Department Of Applied Biological Chemistry Faculty Of Agriculture Niigata University
関連論文
- Synthesis of (±)-Methyl Tuberonate, a Potato Tuber-forming Substance, and Its Epimer
- Four Novel Pseudoalkaloid Taxanes from the Seeds of the Chinese Yew, Taxus chinensis var. mairei
- 4 Pro-R Hydrogen of NADPH was Abstracted for Enzymatic Hydride Transfer by N-Ethylmaleimide Reductase of Yarrowia lipolytica
- Extension of Measurable Region of Object Vibration Phasor in Phase-Modulated TV Holographic Interferometry : Experiment
- New 2(3→20)Abeotaxane and 3, 11-Cyclotaxane from Needles of Taxus cuspidata
- Novel Bicyclic Taxane Diterpenoids from the Needles of Chinese Yew, Taxus Mairei
- Polyoxygenated Cyclohexenes from the Chinese Tree, Uvaria Purpurea(Organic Chemistry)
- Four Polyoxygenated Cyclohexenes from the Chinese Tree, Uvaria Purpurea
- Four Novel Taxane Diterpenoids from the Needles of Japanese Yew, Taxus cuspidata
- Isolation and Structural Determination of a Novel Bicyclic Taxane Diterpene from Needles of the Chinese Yew, Taxus mairei
- A Newly Rearranged 2(3→20) Abeotaxane Diterpene from the Bark o Chinese Yew, Taxus mairei
- Two Novel Taxane Diterpenoids From the Needles of Japanese Yew, Taxus Cuspidata
- Pectins in Extracellular Polysaccharides from a Cell-Suspension Culture of Mentha
- A Novel Rearranged Taxoid from Needles of the Japanese Yew, Taxus cuspidata Sieb. et Zucc.
- New Taxane Diterpenoid from Seed of the Chinese Yew, Taxus yunnanensis
- Synthesis of Macrotetrolide α, a Designed Polynactin Analog Composed of (+)- and (-)-Bishomononactic Acids(Organic Chemistry)
- Synthesis of Southern (C1'-C11') and Eastern (C8-C18) Fragments of Pamamycin-607, an Aerial Mycelium-inducing Substance of Streptomyces alboniger(Organic Chemistry)
- Synthesis of (-)-Methyl Shikimate via Enzymatic Resolution of (1S^*, 4R^*, 5R^*)-4-Hydroxy-6-oxabicyclo [3.2.1] oct-2-en-7-one(Organic Chemistry)
- New 11 (15→1) Abeotaxane, 11 (15→1), 11 (10→9) Bisabeotaxane and 3,11-Cyclotaxanes from Taxus yunnanensis
- Enzymatic Resolution of (±)-Epoxy-β-cyclogeraniol, a Synthetic Precursor for Abscisic Acid Analogs
- Microbial Hydroxylation of (±)- and(-)-(2Z, 4E)-5-(1', 2'-Epoxy-2', 6', 6'-trimethylcyclohexyl)-3-methyl-2,4-pentadienoic acid into (±)-and (-)-Xanthoxin Acid by Cunninghamella echinulata
- Synthesis of (±)-Methyl Bishomononactate, a Monomeric Component of Polynactin Antibiotics
- Preparation of N-Substituted Aryl and Alkyl Carbamates and Their Inhibitory Effect on Oat Seed Germination(Organic Chemistry)
- Phytochemical Study on the Constitution of the Bark of Chinese Yew, Taxus Mairei
- Isomeric Ratio and Level of Xanthoxin in Tomato Plants Measured by a New Analytical Method
- Syntheses of (±)-Methyl 6'α-Demethyl-6'α-cyanoabscisate and (±)-Methyl 6'α-Demethyl-6'α-methoxycarbonylabscisate
- Incorporation of Farnesyl Pyrophosphate Derivertives into Abscisic Acid and Its Biosynthetic Intermediates in Cercospora cruenta
- Extension of Measurable Region of Object Vibration Phasor in Phase-Modulated TV Holographic Interferometry: Experiment