Origin of the In-Plane Anisotropy in Langmuir-Blodgett Films
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概要
- 論文の詳細を見る
An extended model of flow orientation has been developed for analyzing the inplane anisotropy in Langmuir-Blodgett (LB) films by taking into account theviscoelastic nature of a condensed monolayer at the air-water interface as a Binghamplasticity. The model is based on a two-dimensional fluid and a line-sink as represen-ting the monolayer and the substrate, respectively. The predictions from the presentmodel with respect to the dichroic behavior have been experimentally verified employ-ing a mixed LB system of a merocyanine dye and a fatty acid. The model is also consis-tent with the remarks from ESR line-shape analysis reported previously and thosefrom analysis of the optical absorption spectra using the extended dipole theory.These results show that the inner stress due to the velocity gradient in the monolayerduring the deposition is the origin of the in-plane anisotropy.
- 社団法人日本物理学会の論文
- 1989-01-15
著者
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Sugiura K
Department Of Chemistry Graduate School Of Science Tokyo Metropolitan University
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Saito Minoru
Division Of Cellular & Molecular Toxicology National Institute Of Health Sciences
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KURODA Shin-ichi
Electrotechnical Laboratory
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SAITO Kazuhiro
Tochigi Research Laboratories of Kao Corporation
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SATO Michio
Div. of Medical Devices National Institute of Hygienic Sciences
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SAITO Kazuhiro
Electrotechnical Laboratory
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Sugi Michio
Electrolechnical Laboratory
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IKEGAMI Keiichi
Electrotechnical Laboratory
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SAITO Mitsuyoshi
Electrotechnical Laboratory
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MINARI Naoto
Electrotechnical Laboratory
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Ikegami K
Department Of Chemical Engineering And Materials Science Faculty Of Engineering Doshisha University
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