Electrical Conduction of Regioregular and Regiorandom Poly(3-hexylthiophene) Doped with Iodine(Condensed Matter : Electronic Structure, Electrical, Magnetic and Optical Properties)
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概要
- 論文の詳細を見る
The electrical conduction of regioregular poly(3-hexylthiophene) (RR-P3HT) and regiorandom poly(3-hexylthiophene) (RRa-P3HT) doped with iodine is studied as a function of doping level. The electrical conductivity shows the thermally-activated behavior at low doping levels below 10% for RR-P3HT and 18% for RRa-P3HT. At high doping levels higher than 10% for RR-P3HT and 20% for RRa-P3HT, the electrical conductivity shows the three-dimensional variable-range hopping. The change in the conduction mechanism is explained qualitatively in terms of the growth of the density of states at the Fermi level and the dimensional crossover of the conduction path. The difference in the doping levels where the change occurs in RR-P3HT and RRa-P3HT is understood in terms of the carrier localization length, that is, the spatial extent of polaronic excitations in these polymers.
- 社団法人日本物理学会の論文
- 2005-12-15
著者
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ITO Hiroshi
Department of Internal Medicine, Division of Cardiovascular Medicine, Akita University Faculty of Me
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Sugiura K
Department Of Chemistry Graduate School Of Science Tokyo Metropolitan University
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KURODA Shin-ichi
Department of Applied Physics,Graduate School of Engineering,Nagoya University
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KURODA Shin-ichi
Electrotechnical Laboratory
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Kuroda Shin‐ichi
Department Of Applied Physics Nagoya University
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Kuroda Shin-ichi
Department Of Applied Physics Nagoya University
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SUGIURA Ken-ichi
Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University
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MARUMOTO Kazuhiro
Department of Applied Physics, Graduate School of Engineering, Nagoya University
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Ito Hiroshi
Department Of Cardiovascular And Respiratory Medicine Akita University Graduate School Of Medicine
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Kuroda S
Department Of Chemistry Graduate School Of Science Tokyo Metropolitan University
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UKAI Sota
Department of Applied Physics, Nagoya University
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Ukai S
Department Of Applied Physics Nagoya University
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Marumoto K
Department Of Applied Physics Nagoya University
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Marumoto Kazuhiro
Department Of Applied Physics Nagoya University
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Ito Hiroshi
Department Neurosurgery Tokyo Medical College
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