ESR Detection of Induced Spin Moments in Halogen-Bridged Mixed-Metal Complexes Ni_<1-y>Pd_x(chxn)_2Br_3(Condensed Matter : Electronic Structure, Electrical, Magnetic and Optical Properties)

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概要

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• ESR measurements have been performed on single crystals of the quasi-one-dimensional halogen-bridged mixed-metal complexes Ni_<1-y>Pd_x(chxn)_2Br_3, where on-site Coulomb interaction (Ni^<3+> case) and electron-phonon interaction (Pd^<2+>-P^<4+> case) are competing with each other. Monotonic decrease of principal g-values from g^<Ni>_<max> = 2.188 to g^<Pd>_<max> = 2.133 was observed as x increases. This indicates that the magnetic Pd^<3+> ions with smaller g-value than that of Ni^<3+> are induced from non-magnetic Pd^<2+>-Pd^<4+> chain, which is consistent with the previously observed spin susceptibility enhancement in this system. In addition, monotonic decrease of the ESR linewidth is observed as x increases indicating the contribution of Pd^<3+> ions with longer spin-lattice relaxation time T_1D, which is supported by using isomorphic chlorine complexes Ni(chxn)_2Cl_3 and Pd(chxn)_2Cl_3.

• 社団法人日本物理学会の論文
• 2002-05-15

著者

• 山下 護

  徳島工短

• 山下 護

  Department Of Physics Engineering Faculty Of Engineering Mie University

• Sugiura K

  Department Of Chemistry Graduate School Of Science Tokyo Metropolitan University

• Tabata Hitoshi

  The Institute Of Science And Industrial Research Osaka University

• YAMASHITA Masahiro

  Faculity of Science, Toyko Metropolitan University and PREST(JST)

• KURODA Shin-ichi

  Department of Applied Physics,Graduate School of Engineering,Nagoya University

• Kuroda Shin‐ichi

  Department Of Applied Physics Nagoya University

• Kuroda Shin-ichi

  Department Of Applied Physics Nagoya University

• Yamashita Makoto

  Department Of Applied Physics Osaka University

• Tanaka H

  The Institute Of Scientific And Industrial Research Osaka University

• SUGIURA Ken-ichi

  Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University

• TANAKA Hisaaki

  Department of Applied Physics, Graduate School of Engineering, Nagoya University

• MARUMOTO Kazuhiro

  Department of Applied Physics, Graduate School of Engineering, Nagoya University

• MANABE Toshio

  Faculty of Science, Tokyo Metropolitan University

• Kuroda S

  Department Of Chemistry Graduate School Of Science Tokyo Metropolitan University

• Manabe Toshio

  Faculty Of Science Tokyo Metropolitan University

• Marumoto K

  Department Of Applied Physics Nagoya University

• Marumoto Kazuhiro

  Department Of Applied Physics Nagoya University

• Yamashita Masahiro

  Faculity Of Science Toyko Metropolitan University And Prest(jst)

• Yamashita Masahiro

  Department Of Chemistry Faculty Of Science Tokyo Metropolitan University

• Tanaka Hisaaki

  Department Of Applied Physics Nagoya University

• YAMASHITA Mamoru

  Department of Applicad Physics, Faculty of Engineering Nagoya University

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