Formation of Microstructures and Continuous Heating and Time–Temperature Transformation Diagrams of YBa2Cu3O7-x Film Fabricated by Metal Organic Deposition with Trifluoroacetates

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概要

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• The metal organic deposition (MOD) using a precursor solution of trifluoroacetates (TFA) is known to be a promising low cost nonvacuum process for fabricating a high-$J_{\text{c}}$ coated conductor of YBa2Cu3O7-x (YBCO or Y123) film. However, the details of the growth process of Y123 crystals are still unknown. To clarify the growth mechanism of Y123 crystals in the film, the growth processes of Y123 crystals were studied experimentally through transmission electron microscopy (TEM) observations of the specimens quenched during the growth of Y123 crystals on LaAlO3 (LAO) substrates, and the continuous heating and time–temperature transformation (CHT/TTT) diagrams and the growth model of $c/a$-oriented Y123 crystals were obtained. Furthermore, the growth processes of faceted Y123 crystals with various crystal orientations were simulated by the two-dimensional numerical method using $c$- and $a$-axis growth rate functions. The formation processes of microstructures of Y123 crystals were visualized using the growth model and the simulation.

• Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
• 2008-09-25

著者

• MUKAIDA Masashi

  Department of Electrical and Information Engineering, Yamagata University

• Yoshida Jiro

  Department Of Ocean Sciences Tokyo University Of Fisheries

• Mori Nobuyuki

  Department Of Cardiovascular Disease Research Eisai Tsukuba Research Laboratories

• Teranishi Ryo

  Department Of Materials Science And Engineering Faculty Of Engineering Kyushu University

• Yamada Kazuhiro

  Department Of Applied Physics And Physico-informatics Faculty Of Science And Technology Keio University

• Tada Keisuke

  Department of Materials Physics and Chemistry, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

• Mukaida Masashi

  Department of Materials Science and Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

• Yoshida Jiro

  Department of Materials Physics and Chemistry, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

• YAMADA Kazuhiro

  Department of Agricultural Chemistry, Tokyo University of Agriculture

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