A stereoselective total synthesis of methyl .ALPHA.-DL-daunosaminide.
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概要
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Starting from crotonoyl chloride, methyl α-DL-daunosaminide was synthesized through the <I>cis</I> hydroxylation of a key intermediate, 1,1-ethylenedioxy-4-hexen-3-one, followed by oximation, catalytic hydrogenation (Pt, AcOH), and treatment with MeOH/HCl.
- 公益社団法人 日本化学会の論文
著者
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Nakamura Yasuo
Department Of Biocybernetics Faculty Of Engineering Niigata University
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Matsumoto Takeshi
Department Of Biology Faculty Of Science Kumamoto University
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TAKAHASHI Koji
Departent of Materials Science and Engineering,Faculty of Engineering,Yamagata University
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Iwataki Isao
Department of Chemistry, Faculty of Science, Hokkaido University
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Takahashi Koji
Department of Chemistry, Faculty of Science, Hokkaido University
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