Synthesis of 5,5-Dimethyl-4-acetoxy-2-cyclopentenone and 5-Methyl-<I>t</I>-5-acetoxymethyl-<I>r</I>-4-acetoxy-2-cyclopentenone Intermediates for Illudin M and S

スポンサーリンク

概要

• 論文の詳細を見る

• 5,5-Dimethyl-4-acetoxy-2-cyclopentenone and 5-methyl-<I>t</I>-5-acetoxymethyl-<I>r</I>-4-acetoxy-2-cyclopentenone, intermediates for illudin M and S respectively, have been synthesized from ethyl adipate.

• 公益社団法人 日本化学会の論文

著者

• Sakan Fujio

  Department Of Materials Science And Engineering Faculty Of Engineering Fukui University

• Shirahama Haruhisa

  Department Of Chemistry Faculty Of Science Hokkaido University

• Kagawa Shohei

  Department Of Clinical Pathology And Clinical Laboratory Hyogo College Of Medicine

• Matsumoto Takeshi

  Department Of Biology Faculty Of Science Kumamoto University

• Saito Kenichi

  Department Of Kampo Medicinal Science Hokkaido College Of Pharmacy

• ICHIHARA Akitami

  Department of Agricultural Chemistry, Faculty of Agriculture, Hokkaido University

• Hashimoto Hisanobu

  Department of Chemistry, Faculty of Science, Hokkaido University

• Shin Hyonsobb

  Department of Chemistry, Faculty of Science, Hokkaido University

• Nishida Shuji

  Department of Chemistry, Faculty of Science, Hokkaido University

• Matsumoto Sojiro

  Department of Chemistry, Faculty of Science, Hokkaido University

• Saito Kenichi

  Department of Chemistry, Faculty of Science, Hokkaido University

• Sakan Fujio

  Department of Chemistry, Faculty of Science, Hokkaido University

関連論文

• Elevated levels of soluble fibrin in patients with venous thromboembolism
• Negative predictive value of D-dimer for diagnosis of venous thromboembolism
• Biomechanical Analysis of TMJ Soft Tissues under Asymmetric Jaw Movement(3D1 Dental Biomechanics)
• P-06 TRANSPORT MODEL OF PHYSIOLOGICAL SUBSTANCES IN CORTICAL BONE THROUGH POROUS CANAL NETWORK
• Three-dimensional quantitative analysis of glomerular microcirculatoion in diabetic nephropathy using syncrotron radiation X-ray micro-CT
• Novel Cyclohexene Compound from Lasiodiplodia theobromae IFO 31059
• Metabolism and Transport of [2-^C](±) Jasmonic Acid in the Potato Plant
• Four New Polyacetylenic Glucosides, Methyl β-D-Glucopyranosyl Helianthenate C-F, from Jerusalem Artichoke (Helianthus tuberosus L.)
• Tuber-forming Substances in Jerusalem Artichoke (Helianthus tuberosus L.)
• A Novel Sesquiterpene, Tuberonone, from Solanum tuberosum L.
• Macrophomate Synthase: Characterization, Sequence, and Expression in Escherichia coli of the Novel Enzyme Catalyzing Unusual Multistep Transformation of 2-Pyrones to Benzoates^1
• Efficient Degradation of Tautomycin to a Useful Synthetic Intermediate
• Novel Heinz Body Hemolysis Factors in Onion (Allium cepa)
• Syntheses and Potato Tuber-inducing Activity of Coronafacic Acid Analogues
• Efficient Syntheses of the OPC Homologous Series, OPC-1:0, -3:0, -4:0, -5:0, -6:0, -7:0, and -8:0
• Asymmetric Total Syntheses of (+)-Coronafacic Acid and (+)-Coronatine
• Digital Radiographic Quantification of Myocardial Blood Flow Around a Transmyocardial Laser Channel in Rabbit Hearts
• An mRNA of Tobacco Cell, Which Is Rapidly Inducible by Methyl Jasmonate in the Presence of Cycloheximide, Codes for a Putative Glycosyltransferase
• Daily Changes of Nutritional Status in Partially Hepatectomized Rats Receiving Total Parenteral Nutrition(Food & Nutrition)
• Solanapyrones, Phytotoxins Produced by Alternaria solani : Biosynthesis and Isolation of Minor Components
• Pharmacological properties of traditional medicine (XXXI) : Anxiolytic effect of Hangeshashinto and the combinations of its major constituents on rat experimental colitis
• Coronary microcirculation : Physiology and mechanics
• High-intensity signals in the basal ganglia from gadolinium-enhanced T1-weighted MRI as an early change in toxoplasma encephalitis in an AIDS patient
• Microcirculatory heterogeneity of myocardial oxygen supply-consumption balance and flow in crystalloid-perfused rat hearts under hypoxia
• A New Proposal for Crossing Two or More Sheaths through Single Trans-Septal Puncture in Ablation of Atrial Fibrillation : Experience with Steerable Introducer
• Pretreatment of Immobilized Candida antarctica Lipase for Biodiesel Fuel Production from Plant Oil
• Biodiesel Fuel Production from Plant Oil Catalyzed by Rhizopus oryzae Lipase in a Water-Containing System without an Organic Solvent
• Importance of Imaginary Chemical Potential for QCD Phase Diagram in the PNJL Model(QCD Phase Diagram,New Frontiers in QCD 2010-Exotic Hadron Systems and Dense Matter-)
• Myocardial microvascular perfusion after transfusion of liposome-encapsulated hemoglobin evaluated in cross-circulated rat hearts using tracer digital radiography
• Effect of Artificial Red Blood Cells on Renal Microcirculation and Tissue Oxygen in DIC Rats(Thrombosis/Thrombolysis 2 (IHD), The 69th Annual Scientific Meeting of the Japanese Circulation Society)
• Successful Treatment of Intracardiac Progression and Metachronous Multiple Brain Metastases from Primary Lung Cancer
• Influence of the hypogonadism (hgn) locus on female reproduction and ovarian development in an altered genetic background
• Teratogenic effect of static magnetic field on mouse fetuses. (DEVELOPMENT AND REPRODUCTION) (GENERAL SESSION BY POSTER PRESENTATION) (Proceedings of the 30th Annual Meeting)
• Developmental disruption by bisphenol A in early chick embryos. (DEVELOPMENT AND REPRODUCTION) (GENERAL SESSION BY POSTER PRESENTATION) (Proceedings of the 30th Annual Meeting)
• Direct Transformation of Unprotected Sugars to Aryl 1-Thio-β-glycosides in Aqueous Media Using 2-Chloro-1,3-dimethylimidazolinium Chloride
• A New Glycosphingolipid from the Red Alga Corallina pilulifera
• Colloidal Osmotic Pressure in Chronic Subdural Hematoma
• Effect of D-Glucosamine on the Functional Maturation of Cultured B Cells of the Neonatal Rat
• STUDIES ON GLUCORECEPTOR. I. SPECIFIC BINDING OF D-GLUCOSE TO PARTIALLY PURIFIED MEMBRANE OF RAT ISLETS OF LANGERHANS
• Is the Ryukyu subduction zone in Japan coupled or decoupled? : The necessity of seafloor crustal deformation observation
• Evaluation of Peening Intensity of Cavitation Shotless Peening by Using Almen Strip(Student Poster Session)
• Sensitized Effect of Prestimulation on Insulin Release from the Perifused Rat Islets with a Slow-Rise Glucose Stimulation
• A New Approach to Kinetic Analysis of Glucose-Induced Insulin Release by Hills Equation
• Insulin Receptors in Rabbit Erythrocyte
• Stereochemistry of Bicyclohumulenediol and Equilibrium between Two Humulene Epoxides II and III. Novel Interconversion of Two Cycloundecatriene Epoxides through Transnnular Bond Formation
• Isolation of L-N-[2-(3-Pyridyl)ethyl]-glutamic Acid from the Poisonous Mushroom Clitocybe acromelalga. A Possible Intermediate in the Biogenesis of Acromelic Acids
• B-5-4 Structure of Lampterol(Terpenoids)
• Infrared Polarized Reflection Spectra of SrTiO_3 Thin Films on Metal/Si
• An Equivalence Checking Method for C Descriptions Based on Symbolic Simulation with Textual Differences(Simulation and Verification, VLSI Design and CAD Algorithms)
• Prevention of coronary slow flow/no reflow during percutaneous coronary intervention by the use of embolic protection device, 'Filtrap'
• Mg-Promoted Stereoselective Desulfonation of β-Arylvinyl Sulfone Derivatives
• Effect of Acetyl-phosphate and Pyridoxalphosphate on the Induced Synthesis of Peroxidase in Pseudomonas aeruginosa
• Mechanical Properties of Single Trabecula at Microscale : Elastic Modulus, Hardness and X-ray Diffraction Intensity(Micro- and Nano-biomechanics)
• Dynamics of Insulin and Cyclic Adenosine 3, 5-monophosphate Release from the Perifused Rat Islets of Langerhans under a Slow-rise Stimulation with D-Glucose and Its Anomers
• Insulin Release and Metabolism of Calcium, Adenine and Adenosine 3, 5-cyclic monophosphate
• Insulin Release and Efflux of [32P] Phosphate from Islets of Rat Langerhans Treated with Iodoacetic Acid and the Anomers of D-glucose
• Impact of chronic cyanosis and reoxygenation on the microheterogeneity of the myocardial blood flow : digital radiographic study in neonatal rats
• Increased fibrinolysis increases bleeding in orthopedic patients receiving prophylactic fondaparinux
• Monitoring for anti-Xa activity for prophylactic administration of Fondaparinux in patients with artificial joint replacement
• Frequent association of thrombophilia in cerebral venous sinus thrombosis
• Water Analysis by Laser-Induced Shock Wave Plasma Spectroscopy Using Re-crystallized KBr Powder Confined in a Cylindrical Tube
• The crystal and molecular structure of grayanotoxin XVIII. A new minor diterpene from Leucothoe Grayana Max.
• The crystal and molecular structure of grayanotoxin XIX. A new minor diterpene from Leucothoe grayana Max.
• Structures and Phytotoxicity of Metabolites from Valsa ceratosperma
• Δ9(10)-Octal-1-one and its Molecular Compound
• The effect of 2-deoxy-D-glucose on insulin release by neonatal rat B cells in culture.
• Efficacy of Early Intravenous Immunoglobulin for Eosinophilic Granulomatosis with Polyangiitis with Drastically Progressive Neuropathy: A Synopsis of Two Cases
• A stereoselective total synthesis of methyl .ALPHA.-DL-daunosaminide.
• Molecular structure of 5.BETA.,6.BETA.-isopropylidenedioxy-15,16,17-trinorgrayan-10(20)-ene-3,14-dione as revealed by X-ray methods.
• Synthesis of Alkoxycyclopropane Derivatives, Intermediates in the Synthesis of Hirsutic Acid
• The crystal and molecular structure of pikromycin.
• Evaluation of Viscoelastic Property of Articular Cartilage Based on Mechanical Model Considering Tissue Microstructure
• X-ray structure of (10R)-10-bromo-10-deoxyhexahydrolaurefucin.
• The crystal and molecular structure of the photodimer of biphenylene.
• X-Ray Crystal Structure of Pyrenocine A, a Phytotoxin from Pyrenochaeta terrestris
• The crystal and molecular structure of palythine trihydrate.
• X-Ray structure of (1RS, 5RS, 7SR)-1-acetoxy-7-cyano-5-methylbicyclo-(3.2.0)heptan-2-one, a photocycloadduct of 2-acetoxy-3-methyl-2-cyclopenten-1-one and acrylonitrile.
• Trimethylsilyl triflate induced reaction of humulene 6,7-epoxide. Cyclization to 5-hydroxy-4,8,11,11-tetramethyltricyclo(6.3.0.02,4)undec-9-ene.
• Structure and Biological Activity of Bottrospicatol, a Novel Monoterpene Produced by Microbial Transformation of (-)-cis-Carveol
• Synthesis of hypacrone.
• Various acceleration conditions of Pummerer reaction observed in the total synthesis of illudins.
• The absolute configuration of 4,6-decadiyne-1,3,8-triol isolated from Gymnopilus spectabilis.
• Enzymatic synthesis of new pyridine nucleosides. Clitidine and its amide derivative.
• A cyclization of humulene by means of a mercuric salt in aceto- and benzonitrile.
• Synthesis of 5,5-Dimethyl-4-acetoxy-2-cyclopentenone, an Intermediate in the Total Synthesis of Illudin M, through Sulfur Compounds. A Novel Intramolecular Migration of Ethylenedioxy Group
• Stereospecific Reductions of Isoilludin S and M on Alumina Chromatography
• Serotobenine, a Novel Phenolic Amide from Safflower Seeds (Carthamus tinctorius L.)
• The Molecular and Crystal Structure of the p-Bromobenzoate of an Unusual Birch Reduction Product
• The Crystal Structure of d,l-1,1,4aα-Trimethyl-2α-hydroxy-8α-acetoxy-1,2,3,4,4α,5,6,7,8,9-decahydrophenanthrene
• Synthesis of 5,5-Dimethyl-4-acetoxy-2-cyclopentenone and 5-Methyl-t-5-acetoxymethyl-r-4-acetoxy-2-cyclopentenone Intermediates for Illudin M and S
• Lead tetraacetate oxidation of humulene and conformational analysis of the produced humulatrienediols.
• The crystal and molecular structure of staurosporine, a new alkaloid from a Streptomyces strain.
• The crystal and molecular structure of albocycline.
• The crystal and molecular structure of 7,8-epoxyhalochamigrene.
• X-ray structure determination of (-)-obtusane, a new sesquiterpene from the red alga, Laurencia nipponica Yamada.
• The conformations of (Z)-2,3,4,7,8,9-hexahydrooxonin and (Z)-cyclononene. X-ray structure determinations of isolaurallene and neolaurallene, and force-field calculations.
• MINDO/3 study of 7-norbornyl, 7-norbornenyl, and 7-norbornadienyl cations.
• Synthesis and Conformation of Cyclopropane Intermediates in the Total Synthesis of Illudin M and S
• New A-nor-B-homo-ent-kauranoids (grayanotoxin XVI and XVII) from Leucothoe grayana Max.
• Presence of antiphospholipid antibody is a risk factor in thrombotic events in patients with antiphospholipid syndrome or relevant diseases

もっと見る 閉じる

スポンサーリンク