EXAFS study on one-dimensional halogen-bridged mixed-metal (Pd, Pt) mixed-valence complexes.

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概要

• 論文の詳細を見る

• The EXAFS spectra of [Pd(en)<SUB>2</SUB>X<SUB>2</SUB>Pt(en)<SUB>2</SUB>](ClO<SUB>4</SUB>)<SUB>4</SUB> (en=ethylenediamine, X=Cl, Br, and I) were measured for Pd K and Pt L<SUB>III</SUB> edges. The Fourier transforms of the Pd K and Pt L<SUB>III</SUB>- edge EXAFS show clearly that the halogen atoms are forming a chemical bond only to Pt(IV) and Pt–Cl, Pt–Br, and Pt–I bond lengths are 2.34, 2.47, and 2.83Å respectively.

• 公益社団法人 日本化学会の論文

著者

• ASAKURA Kiyotaka

  Department of Chemistry and State Key Laboratory of Physical Chemistry for Solid Surface, Xiamen Uni

• Kikuchi Koichi

  Department Of Chemistry Tokyo Metropolitan University

• Ikemoto Isao

  Department Of Chemistry Faculty Of Science Tokyo Metropolitan University

• Kosugi Nobuhiro

  Department Of Chemistry University Of Tokyo

• Yakushi Kyuya

  Department Of Chemistry Faculty Of Science University Of Tokyo

• Kuroda Haruo

  Department Of Chemistry Faculty Of Science The University Of Tokyo

• Yamashita Masahiro

  Laboratory Of Viral Pathogenesis Institute For Virus Research Kyoto University

• ASAKURA Kiyotaka

  Department of Chemistry, Faculty of Science, The University of Tokyo

• Iwai Kumiko

  Department of Chemistry, Faculty of Science, Tokyo Metropolitan University

• Nomura Masaharu

  Pnoton Factory, National Laboratory for High Energy Physics

• Ikemoto Isao

  Department of Chemistry and Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo

• Asakura Kiyotaka

  Department of Chemistry and Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo

• Kuroda Haruo

  Department of Chemistry and Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo

• Yamashita Masahiro

  Laboratory of Chemistry, College of General Education, Kyushu University

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