Reflectance spectra of the 1:1 salts of bis(methylenedithio)tetrathiafulvalene(BMDT-TTF): Estimation of the on-site coulomb energy.
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概要
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Polarized reflectance spectra were measured on the single crystals of (BMDT-TTF)AsF<SUB>6</SUB> and (BMDT-TTF)SbF<SUB>6</SUB>. The charge-transfer band was observed along the stacking direction in the crystals of (BMDT-TTF)AsF<SUB>6</SUB>, while in the crystal of (BMDT-TTF)SbF<SUB>6</SUB> the charge-transfer band was found not only along the stacking direction but also along the S···S direction nearly parallel to the short axis of the BMDT-TTF molecule. The effective on-site Coulomb energies and the transfer integrals of these salts were estimated by analyzing the charge-transfer bands.
- 公益社団法人 日本化学会の論文
著者
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Kato Reizo
Department Of Chemistry Faculty Of Science Saitama University
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Yakushi Kyuya
Department Of Chemistry Faculty Of Science University Of Tokyo
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Kuroda Haruo
Department Of Chemistry Faculty Of Science The University Of Tokyo
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Kobayashi Hayao
Department Of Chemistry Faculty Of Science Toho University
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Kobayashi Akiko
Department Of Biopharmaceutics Meiji Pharmaceutical University
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Kobayashi Akiko
Department of Chemistry, Faculty of Science, University of Tokyo
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Yoshitake Michiko
Department of Chemistry, Faculty of Science, University of Tokyo
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Yoshitake Michiko
Department of Chemistry, Faculty of Science, the University of Tokyo
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Kuroda Haruo
Department of Chemistry and Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo
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Kato Reizo
Department of Chemistry, Faculty of Science, Toho University
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