EXAFS spectroscopy of some iron(III) compounds by use of dispersive-type in-laboratory X-ray spectrometer.
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概要
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A dispersive-type in-laboratory EXAFS spectrometer was constructed by combining a transmission-type dispersing crystal and a position-sensitive proportional counter. FeK absorption spectra were measured by use of this apparatus on FeCl<SUB>3</SUB>·6H<SUB>2</SUB>O, Fe(ClO<SUB>4</SUB>)<SUB>3</SUB>·6H<SUB>2</SUB>O and anhydrous FeCl<SUB>3</SUB>. Discussion is given on the results obtained from the analyses of observed EXAFS data concerning the structure around Fe ions in these compounds. AsI<SUB>3</SUB>-like structure is proposed for anhydrous FeCl<SUB>3</SUB>.
- 公益社団法人 日本化学会の論文
著者
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Matsushita Tadashi
Photon Factory National Laboratory For High Energy Physics
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Kuroda Haruo
Department Of Chemistry Faculty Of Science The University Of Tokyo
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Nomura Masaharu
Department Of Surgery Tokyo Metropolitan Ebara Hospital
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Kaminaga Ukyo
Photon Factory, National Laboratory for High Energy Physics
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Asakura Kiyotaka
Department of Chemistry and Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo
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Kohra Kazutake
Photon Factory, National Laboratory for High Energy Physics
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Kuroda Haruo
Department of Chemistry and Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo
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Nomura Masaharu
Department of Chemistry and Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo
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