X-ray photoelectron spectroscopy of chloromethanes and chloroethanes.

スポンサーリンク

概要

• 論文の詳細を見る

• X-Ray photoelectron spectra of chloromethanes (CH<SUB>4−<I>n</I></SUB>Cl<I><SUB>n</SUB></I>, <I>n</I>=2,3,4) and chloroethanes (CH<SUB>3</SUB>CH<SUB>3−<I>n</I></SUB>Cl<I><SUB>n</SUB></I>, <I>n</I>=1,2,3) in vapor phase were observed employing Mg <I>K</I>α radiation. The observed Cls binding energies were analyzed by means of Siegbahn's electrostatic potential model and charge densities calculated by the CNDO/2 method, and the effects of inclusion and exclusion of Cl 3d atomic orbitals in the basis set of the CNDO/2 calculation is critically investigated. The assignment of all valence electron levels of above molecules were performed with the aids of the CNDO/2 calculations incorporated with Gelius' intensity model and the reported data of ultraviolet photoelectron spectroscopy.

• 公益社団法人 日本化学会の論文

著者

• Ohta Toshiaki

  Department Of Chemistry Faculty Of Science University Of Tokyo

• Kuroda Haruo

  Department of Chemistry and Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo

関連論文

• Analysis of de Haas-van Alphen Oscillations and Band Structure of an Organic Superconductor, θ-(BEDT-TTF)_2I_3
• Energy Dispersive Near Edge X-Ray Absorption Fine Structure in the Soft X-Ray Region: A New Technique to Investigate Surface Reactions
• Magnetic Interaction between Adsorbed NO and fcc Co (001) Thin Films Studied by X-ray Magnetic Circular Dichroism
• Observation of O K-Edge X-Ray Magnetic Circular Dichroism of CO Adsorbed on an Ultrathin Co/Cu(001)Film
• Structural and Electronic Properties of Adsorbed Thiophene on Cu(111) Studied by S K-Edge X-Ray Absorption Spectroscopy
• Anharmonicity of the Bending and Stretching Vibrations Observed in Extended X-Ray Absorption Fine Structure of Tetrahedral Molecules
• Local Structures of Carbon Thin Films Synthesized by the Hot Filament Chemical Vapor Deposition Method X-Ray-Absorption Near-Edge Structure and Raman Spectroscopic Studies
• Temperature-Dependent Br K-Edge EXAFS Study on AgBr_xCl_ Solid Solutions
• Applicability of the Soft X-Ray Standing-Wave Method to Surface Structure Determination
• XANES and Raman Spectroscopic Studies of Diamond Films Synthesized by Hot Filament CVD
• Bromine Adsorption on Supported Palladium Ultrafine Particles Studied by Br K-Edge EXAFS Spectroscopy
• Surface Structure of N/Pd(100)-c(2 × 2) Determined by Tensor Low Energy Electron Diffraction Analysis
• Structure, Composition, and Vibrational Property of Iodine-Doped Polyvinyl Alcohol Studied by Temperature-Dependent I K-Edge Extended X-Ray-Absorption Fine Structure
• Local Structures of RbBr_xCl_ and CuBr_xCl_ Solid Solutions Studied by Temperature-Dependent Br K-Edge Extended X-Ray-Absorption Fine-Structure Spectroscopy
• Temperature-Dependent EXAFS Study on Supported Silver and Palladium Clusters: Comparison of Their Interatomic Potentials with Those of Bulk Metals
• Temperature-Dependent EXAFS Study on Supported Silver and Palladium Clusters
• Electrical Resistivity under High Pressure and Upper Critical Magnetic Field of the Molecular Superconductor α-(EDT-TTF)[Ni (dmit)_2]
• Electrical and Optical Properties of α-(BETS)_2I_3 and α-(BEDT-STF)_2I_3
• Effect of the Soft X-Ray Standing Wave Fields on the Total Electron Yield Spectra from an InP Crystal
• High Field Magnetoconductivity in (TMTSF)_2CIO_4
• Anomalous Decrease of the Work Function of a Carbide-modified W(110) Surface Induced by Hydrogen Chemisorption
• S(KLL) Anger Resonancelike Phenomena for Solid Samples
• First Ambient-pressure Superconductor Based on Ni(dmit)2, α-EDT-TTF[Ni(dmit)2]
• Molecular Photoionization Cross Sections and Their Angular Distributions Calculated by OPW, EOPW and HOPW Methods : X-RAY AND XUV ABSORPTION SPECTRA
• Evaluation of Tensile Strength of Unresin Continuous Carbon Fiber Cables as Tensile Reinforcement for Concrete Structures
• Reflectance Spectra of k-(BEDT-TTF)_2I_3:Electronic Structure of Dimeric BEDT-TTF Salts
• Temperature Dependence of the Polarized Reflectance Spectra of the θ-Type of Bis (ethylenedithio) tetrathiafulvalenium Triiodide θ-(BEDT-TTF)_2I_3:Estimation of Band Parameters
• Magnetization and Meissner Effect of Organic Superconductor θ-(BEDT-TTF)_2I_3
• Remarks on the Vacancy Mechanisms in Ion Implantation
• -221-COMBINED VALVULAR AND CORONARY ARTERY SURGERY : AN EXPERIENCE OF 4 CASES
• X-Ray Photoelectron Spectroscopy and X-Ray Absorption Near Edge Structure Study of Structural Change of Perhydropolysilazane to Silicon Nitride by Heat Treatment
• Temperature Dependence of Extended X-Ray Absorption Fine Structure of CuBr^-_2:Dynamical Effect of the Scattering Amplitude
• Optimal Time for Replacement Surgery in Chronic Aortic Valve Disease : PANEL DISCUSSION ON VARIOUS PROBLEMS IN VALVE REPLACEMENT
• Photoinduced Processes of Solid Aromatic Compounds by Mid-IR Free Electron Laser
• X-ray photoelectron spectroscopy of sodium-doped polyacetylene.
• Studies on the valence state of iron atoms in the mixed-valence binuclear ferrocenes by X-ray absorption near edge structure (XANES) and by X-ray photoelectron spectroscopy (XPS).
• Electronic interactions in triple exciplex of the 1,4-dicyanobenzene and naphthalene system.
• EXAFS study on one-dimensional halogen-bridged mixed-metal (Pd, Pt) mixed-valence complexes.
• Temperature dependence of the reflectance spectra of the single crystals of bis(ethylenedithio)tetrathiafulvalenium salts. .ALPHA.-(BEDT-TTF)3(ReO4)2 and .ALPHA.-(BEDT-TTF)2I3.
• The reflectance spectra of (BEDT-TTF)5Hg3Br11 and (BEDT-TTF)HgBr3. The estimation of effective on-site Coulomb interaction.
• Dopant structure in FeCl3-doped polyacetylene studied by X-ray absorption spectroscopy and X-ray photoelectron spectroscopy.
• Reflectance spectra of the 1:1 salts of bis(methylenedithio)tetrathiafulvalene(BMDT-TTF): Estimation of the on-site coulomb energy.
• Core-electron Spectra of Mono-substituted Benzenes Obtained by the Gas-phase X-Ray Photoelectron Spectroscopy
• Interaction between Electron Donor and Acceptor: MINDO/2 Calculations on the Ammonia–I2, Benzene-I2 and Benzene–TCNE Systems
• Electrochemical preparation and characterization of the radical salts of (phthalocyaninato)nickel, NiPc(SbF6)0.5, and NiPc(AsF6)0.5.
• Sulfur K-edge absorption spectra of Na2SO4, Na2SO3, Na2S2O3, and Na2S2Ox (x=5-8).
• Preparation, crystal structure, and solid state properties of highly conductive (phthalocyaninato) platinum radical salts: PtPc(ClO4)0.5 and PtPc(AsF6)x.
• X-Ray Photoelectron Spectroscopy of p-Benzoquinone, Hydroquinone and Their Halogen-Substituted Derivatives
• EXAFS studies of the behavior of Rh6(CO)16 supported on .GAMMA.-Al2O3 surface.
• Evaluation of the Redox Behavior of Hydrous Ruthenium Oxides: Effect of Temperature and Acid Concentration on the Electrochemical Behavior of Layered Ruthenium Oxide
• Preparation and characterization of (tetrabenzoporphyrinato)nickel hexafluoroarsenate, (NiTBP)3(AsF6)2(C10H7Cl). A new type of metallomacrocyclic radical salts.
• Structure and optical spectrum of (TMTTF)2IO4. The role of Coulomb interaction.
• EXAFS spectroscopy of some iron(III) compounds by use of dispersive-type in-laboratory X-ray spectrometer.
• Charge-transfer bands of the mixed molecular complex, (anthracene)1-x(phenanthrene)x(1,2,4,5-tetracyanobenzene).
• X-ray photoelectron spectrum of Cr2O5.
• Polarized absorption and reflection spectra of the single crystals of benzidine-7,7,8,8-tetracyano-p-quinodimethane molecular complexes.
• Fe K-edge XANES and EXAFS of the X-ray absorption spectra of FeCl3 aqueous solutions. A structural study of the solute, iron(III) chloro complexes.
• Low-temperature reflection spectra of the single crystals of TCNQ complex salts.
• Reflection spectrum of the single crystal of wurster's blue perchlorate.
• Reflection and photoconduction spectra of the single crystals of perylene-TCNQ 1:1 and 3:1 molecular complexes.
• Solvent inclusion effects on the structure and electrical conductivity of benzidine-TCNQ complex.
• Interpretation of Shake-up Satellites in the X-Ray Photoelectron Spectra of Small Hydride Molecules by One-Center-Expansion ab initio Calculation with Equivalent-Core Approximation
• Temperature dependence of the dielectric constants of potassium-chloranil salt and Wuerster's blue perchlorate.
• Dielectric Constant Measurement on Organic Crystalline Powder
• Polarized Absorption Spectra of Single Crystals of Ion Radical Salts. III. Temperature Dependence of the Crystal Spectra of Potassium-Chloranil
• Electronic structures of meso-ionic azapentalenes studied by X-ray photoelectron spectroscopy.
• The Electronic Structure of the Electron-donor-acceptor System in the Excited State. The Exciplex and the Fluorescent State of EDA Complex
• Semiconductivity and Photoconductivity of TCNQ Crystal
• X-ray photoelectron spectroscopy of chloromethanes and chloroethanes.
• Polarized absorption spectra of single crystals of tetrathiafulvalenium salts.
• Polarized absorption and reflection spectra of the single crystals of 11,11,12,12-tetracyano-2,6-naphthoquinodimethan (TNAP) complexes.
• Hydrate Crystals of Alkali Metal-Chloranil and -Bromanil Salts and Their Optical and Magnetic Properties

もっと見る 閉じる

スポンサーリンク