The Crystal Structure of an <I>N</I>-Methylphenothiazine–7,7,8,8-Tetracyanoquinodimethane Complex, <I>N</I>-MePZT–TCNQ

スポンサーリンク

概要

• 論文の詳細を見る

• Crystals of the 1 : 1 charge-transfer complex of <I>N</I>-MePZT–TCNQ, are monoclinic with those lattice constants: <I>a</I>=10.904, <I>b</I>=13.321, <I>c</I>=7.086 Å, and β=91.06°, and with the space group C2/m. X-ray structure analysis showed that the mixed-stacks of <I>N</I>-MePZT and TCNQ, exist along the c axis. <I>N</I>-MePZT is disordered, and its apparent molecular symmetry is C<SUB>2h</SUB>, taking four possible conformations. The molecular geometry of TCNQ, indicates that the amount of the charge transferred from <I>N</I>-MePZT is very small (<0.2e).

• 公益社団法人 日本化学会の論文

著者

• Kobayashi Hayao

  Department Of Chemistry Faculty Of Science Toho University

関連論文

• Mysterious Paramagnetic States of Fe 3d Spin in Antiferromagnetic Insulator of λ-BETS_2FeCl_4 System(Condensed matter: structure and mechanical and thermal properties)
• Single-Component Molecular Metals as Multiband π-d Systems(Condensed matter: electronic structure and electrical, magnetic, and optical properties)
• Magnetic Structure in the Antiferromagnetic State of the Organic Conductor, (DMe-DCNQI[3,3 : 1]d_7)_2Cu : ^1H-NMR Analysis
• Novel Electronic States of Partially Deuterated (DMe-DCNQI)_2Cu
• Weak Ferromagnetism and Magnetic Anisotropy in Cu Salt of Fully Deuterated DMe-DCNQI, (DMe-DCNQI-d_8)_2Cu
• Giant Metal-Insulator-Metal Transition Induced by Selective Deuteration of the Molecular Conductor, (DMe-DCNQI)_2Cu (DMe-DCNQI = 2,5-dimethyl-N,N'-dicyanoquinonediimine)
• Electrical Resistivity under High Pressure and Upper Critical Magnetic Field of the Molecular Superconductor α-(EDT-TTF)[Ni (dmit)_2]
• Electrical and Optical Properties of α-(BETS)_2I_3 and α-(BEDT-STF)_2I_3
• New Organic Metals Based on BETS Compounds with MX_ Anions (BETS=bis(ethylenedithio)tetraselenafulvalene; M = Ga, Fe, In; X=Cl, Br)
• A New Organic Superconductor, λ-(BEDT-TSF)_2GaCl_4
• New Molecular Superconductor, [Me_2Et_2N] [Pd(dmit)_2]_2
• Superconducting Transition Temperature of the Organic Alloy System. κ-[(BEDT-TTF)_(BEDT-STF)_x]_2Cu[N(CN)_2」Br
• Cu NMR Study in DCNQI-Cu System
• Shubnikov-de Haas Effect in (TMTSF)_2CIO_4
• First Ambient-pressure Superconductor Based on Ni(dmit)2, α-EDT-TTF[Ni(dmit)2]
• Metal Instability of (DMe-DCNQI)_2 Cu Induced by Uniaxial Stress and Enhancement of Electron Mass
• Magnetic and Structural Properties of Mixed-Valence Molecular Conductors (DMeDCNQI)_2Cu and (DMeODCNQI)_2Cu
• Pressure-Induced One-Dimensional Instability in (DMDCNQI)_2Cu
• Reflectance Spectra of k-(BEDT-TTF)_2I_3:Electronic Structure of Dimeric BEDT-TTF Salts
• Temperature Dependence of the Polarized Reflectance Spectra of the θ-Type of Bis (ethylenedithio) tetrathiafulvalenium Triiodide θ-(BEDT-TTF)_2I_3:Estimation of Band Parameters
• Conducting properties of κ-Type Molecular Metals, A New Pd(dmit)_2 Superconductor and Electron Mass Enhancement in DCNQI-Cu Systems : V-A Organic Syntheses : V Organic Superconductors
• Magnetic and Thermal Properties of \lambda-(BETS)2FeCl4 System ---Fe 3d Spin in Antiferromagnetic Insulating Phase---
• Dielectric Properties of Water Chains Incorporated in Porous Coordination Polymer Crystal [Cu(C_6H_4NO_2)_2]
• Single-component Layered Molecular Conductor, [Au(ptdt)_2]
• Evidence of Charge Disproportionation in $\lambda$ Type BETS Based Organic Superconductors
• Synthesis, crystal structure, and physical properties of the charge-transfer complex bis[benzo[1,2-c:3,4-c':5,6-c"]trithiophene]-tetra-fluorotetracyanoquinodimethan, (BTT)2(TCNQF4).
• Orbital Effect on FFLO Phase and Energy Dissipation due to Vortex Dynamics in Magnetic-Field-Induced Superconductor \lambda-(BETS)
• Orbital Effect on FFLO Phase and Energy Dissipation due to Vortex Dynamics in Magnetic-Field-Induced Superconductor λ-(BETS)₂FeCl₄
• Reflectance spectra of the 1:1 salts of bis(methylenedithio)tetrathiafulvalene(BMDT-TTF): Estimation of the on-site coulomb energy.
• The intermolecular interaction of tetrathiafulvalene and bis(ethylenedithio)tetrathiafulvalene in organic metals. Calculation of orbital overlaps and models of energy-band structures.
• The crystal structure of (TMTTF)2ReO4.
• The crystal and molecular structures of bis(ethylenedithio)tetrathiafulvalene.
• Structural studies of partially oxidized one-dimensional bis(oxalato)-platinate salts containing bivalent cations: Ni0.84(Pt(C2O4)2)6H2O.
• Superconductivity and characterization of the high-pressure reaction products of carbon diselenide, CSe2.
• New multi-sulfur 1,2-dithiolene complexes. Preparation, structure, and electrochemical properties.
• Peierls structure of (H3O)0.33Li0.8(Pt(mnt)2)1.67H2O.
• Crystal and molecular structure of tetrabutylammonium bis(1,4-dithiin-2,3-dithiolato)nickelate(III), (Bun4N)[Ni(ddt)2].
• The crystal and band electronic structures of bis(4,5-ethylenedithio-4',5'-(vinylenedithio)tetrathiafulvalenium)hexafluorophosphate, and hexafluoroarsenate (EVT2PF6 and EVT2AsF6).
• Crystal structure and molecular structure of neutral nickel bis(5,6-dihydro-1,4-dithiin-2,3-dithiolate), Ni(dddt)2.
• The crystal structure of tetramethyltetraselenafulvalenium perrhenate, (TMTSF)(ReO4)(C2H3Cl3)0.25.
• The Crystal Structure of Acridinium Bis(7,7,8,8-Tetracyanoquinodimethanide), ARD+(TCNQ)2− and Some Remarks on the Possibility of a Peierls Distortion of a Linear Chain of TCNQ
• An X-Ray Analysis of the Orientational Disorder of N-Methylphenazinium-TCNQ
• The crystal structure of the charge-transfer complex of dibenzotetrathiafulvalene-tetracyanoquinodimethane, DBTTF-TCNQ.
• The Crystal Structure of Tetraiodo-p-benzoquinone
• Phase transitions of the 1:2 complex of N-ethyl-N-methylmorpholinium and 7,7,8,8-tetracyanoquinodimethan, MEM(TCNQ)2 above room temperature.
• The Crystal Structure of an N-Methylphenothiazine–7,7,8,8-Tetracyanoquinodimethane Complex, N-MePZT–TCNQ
• The Crystal Structure of Rb(TCNQ)-II
• Structural studies of commensurate Peierls state of Rb1.67[Pt(C2O4)2] 1.5H2O.
• Band-structure parameters of organic conductors, TSeT2Cl,TTT2I3, and TSeT2SCN.
• Single-component Magnetic Molecular Conductor [Fe(dmdt)_2](dmdt:dimethyltetrathiafulvalenedithiolate
• Dielectric Propersites of the Charge-transfer Complex of Phenothiazine and Trinitrobezene

もっと見る 閉じる

スポンサーリンク