Pressure-induced Crossover from Variable Range Hopping to Electron-Electron Interaction in the Organic Conductor (DOET)_2BF_4(Condensed Matter : Electronic Structure, Electrical, Magnetic and Optical Properties)

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This paper reports the pressure effect on resistivity in the quasi two-dimensional (2D) organic conductor (DOET)_2BF_4 with orientational disorder of BF_4 anions. At ambient pressure, the resistivity shows metal-insulator transition at 80K and 2D variable range hopping (VRH) conduction below 80K. The insulating behavior is suppressed by applying pressure and the temperature dependence of the resistivity shows the crossover from the 2D VRH to the logarithmic divergence as applied pressure increases. From the observation of the positive magnetoresistance, the logarithmic divergence of the resistivity is not attributed to the Anderson localization, but to the effect of the electron-electron interaction. This crossover is simply understood in terms of the screening effect on the random potential by increase of bandwidth due to applied pressure. It is found that a value of sheet conductance at low temperatures above 8 kbar, where the insulating state is almost suppressed, approaches to the minimum conductivity for a metallic state, σ_<min>=e^2/h=1/(25.8kΩ), first proposed by Mott.
社団法人日本物理学会の論文
2006-02-15