The microwave spectra, dipole moments, and two isomers of cyclopentadiene-1-carbonitrile.
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概要
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The microwave spectra of two isomers of cyclopentadiene-1-carbonitrile generated by the pyrolysis of 1<I>H</I>-benzotriazole have been observed in the frequency range from 8.0 to 40.0 GHz. The rotational constants (MHz) have been determined as <I>A</I>=8353.7(9), <I>B</I>=1904.24(1), and <I>C</I>=1565.38(1) for 1,3-cyclopentadiene-1-carbonitrile, and <I>A</I>=8235.0(13), <I>B</I>=1902.07(2), and <I>C</I>=1559.67(2) for 1,4-cyclopentadiene-1-carbonitrile. The dipole moments (Debye) obtained are μ<SUB>a</SUB>=4.15(15), μ<SUB>b</SUB>=0.27(3), and μ<SUB>total</SUB>=4.16(17) for 1,3-cyclopentadiene-1-carbonitrile and μ<SUB>a</SUB>=4.36(25), μ<SUB>b</SUB>=0.77(10), and μ<SUB>total</SUB>=4.42(35) for 1,4-cyclopentadiene-1-carbonitrile.
- 公益社団法人 日本化学会の論文
著者
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Kikuchi Hiromi
Department Of Applied Chemistry Graduate School Of Engineering Tohoku University
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Yamaguchi Ichiro
Department Of Clinical Laboratory Yamagata University School Of Medicine
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Sakaizumi Takeshi
Department Of Chemistry Faculty Of Science Shizuoka University
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Ohashi Osamu
Department Of Chemistry Faculty Of Science And Technology Sophia University
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Kikuchi Hiromi
Department of Chemistry, Faculty of Science and Technology, Sophia University
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