The microwave spectrum of ethyl isocyanate.

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概要

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• The microwave spectrum of ethyl isocyanate, CH<SUB>3</SUB>CH<SUB>2</SUB>NCO, has been obtained in the frequency region from 8.5 to 35.5 GHz. The spectrum identified is attributed to the <I>cis</I> conformation, in which the methyl group eclipses the isocyanato group. The rotational constants in the ground vibrational state obtained are <I>A</I>=14110±3, <I>B</I>=3067.91±0.02, and <I>C</I>=2605.01±0.02 MHz. The dipole moment (μ<SUB>a</SUB>) for this rotamer is 2.81±0.02 D. Four sets of vibrational satellites were observed and assigned to the transitions in the first, second, third, and fourth excited states of the C–N torsional vibration.

• 公益社団法人 日本化学会の論文

著者

• Yamada Osamu

  Department Of Cardiovascular Dynamics National Cardiovascular Center Research Institute

• OHASHI Osamu

  Department of Chemistry, Faculty of Science and Technology, Sophia University

• Yamaguchi Ichiro

  Department Of Clinical Laboratory Yamagata University School Of Medicine

• Sakaizumi Takeshi

  Department Of Chemistry Faculty Of Science Shizuoka University

• Ohashi Osamu

  Department Of Chemistry Faculty Of Science And Technology Sophia University

• Ushida Kyoichi

  Department of Chemistry, Faculty of Science and Technology, Sophia University

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