Microwave spectrum of ethyl isothiocyanate.
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概要
- 論文の詳細を見る
The microwave spectrum of ethyl isothiocyanate, CH<SUB>3</SUB>CH<SUB>2</SUB>NCS, has been obtained in the frequency region from 8.5 to 35 GHz. The spectrum identified is attributed to the <I>cis</I> configuration, namely, the methyl group eclipses the isothiocyanato group. The rotational constants for the ground vibrational state obtained are <I>A</I>=1419±10, <I>B</I>=1799.27±0.02 and <I>C</I>=1612.14±0.02 MHz. The dipole moment of this rotamer is μ<SUB>total</SUB>=3.33±0.03 D (μ<SUB>a</SUB>=3.33±0.03 D, μ<SUB>b</SUB>=0.07±0.02 D). Two sets of vibrational satellites were observed and assigned to the modes of C–N torsion (58±30 cm<SUP>−1</SUP>) and CNC bending (107±30 cm<SUP>−1</SUP>).
- 公益社団法人 日本化学会の論文
著者
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Yamaguchi Ichiro
Department Of Clinical Laboratory Yamagata University School Of Medicine
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Sakaizumi Takeshi
Department Of Chemistry Faculty Of Science Shizuoka University
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Ohashi Osamu
Department Of Chemistry Faculty Of Science And Technology Sophia University
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