The microwave spectrum of anti-acetaldehyde oxime-d.
スポンサーリンク
概要
- 論文の詳細を見る
The microwave spectrum of <I>anti</I>-acetaldehyde oxime-<I>d</I> was investigated in the frequency region from 9 to 36 GHz. The rotational transition lines widely split into the A and E species due to the tunneling of the methyl group through the low potential barrier hindering the internal rotation. The transition lines belonging to the A species were fitted to the rigid rotor Hamiltonian, and the following effective rotational constants in MHz were obtained: <I>A</I><SUB>A</SUB>=17250, <I>B</I><SUB>A</SUB>=6284.33, and <I>C</I><SUB>A</SUB>=4704.96. All the observed transition frequencies were fitted to the Hamiltonian containing perturbation terms to the fourth order in order to obtain the internal-rotation parameters using the principal axis method. The potential barrier, <I>V</I><SUB>3</SUB>, hindering the internal rotation was determined to be 373 cal mol<SUP>−1</SUP>. The dipole moment was determined to be 0.828 D from the Stark effect of the transitions belonging to the A species.
- 公益社団法人 日本化学会の論文
著者
-
Hara Hisao
Department Of Cardiology Toho University Ohashi Medical Center
-
Yamaguchi Ichiro
Department Of Clinical Laboratory Yamagata University School Of Medicine
-
Sakaizumi Takeshi
Department Of Chemistry Faculty Of Science Shizuoka University
-
Ohashi Osamu
Department Of Chemistry Faculty Of Science And Technology Sophia University
-
Onda Masao
Department of Chemistry, Faculty of Science and Technology, Sophia University
-
Noji Keiko
Department of Chemistry, Faculty of Science and Technology, Sophia University
-
Hara Hisao
Department of Chemistry, Faculty of Science and Technology, Sophia University
関連論文
- PJ-469 Predictive Factors of a Favorable Responder after Renal Artery Stenting in Patients with Renal Artery Stenosis(PJ079,Peripheral Circulation/Vascular Disease (Therapy) 2 (H),Poster Session (Japanese),The 73rd Annual Scientific Meeting of The Japanes
- PJ-932 Anatomical characteristics of SFA associates with the development of SFA lesion, independent of risk factors(Peripheral circulation / Vascular disease(10)(H),Poster Session(Japanese),The 72nd Annual Scientific Meeting of the Japanese Circulation So
- OE-262 Outcomes of endovascular treatment for TASC A to D iliac artery lesions(Peripheral circulation/Vascular disease(01)(H),Oral Presentation(English),The 72nd Annual Scientific Meeting of the Japanese Circulation Society)
- PJ-167 High Insulin Level Deteriorates Left Ventricular Salvage Effects after Recanalization of Infarcted AMI(Acute myocardial infarction, clinical (diagnosis/treatment)-8, The 71st Annual Scientific Meeting of the Japanese Circulation Society)
- STUDY ON SYMPATHETIC RESPONSE TO EXERCISE IN PATIENTS WITH HEART DISEASE : Exercise Test, Rehabilitation : 53 Annual Scientific Meeting, Japanese Circulation Society
- EFFECT OF LOCAL CARDIAC SYMPATHECTOMY ON REGIONAL MYOCARDIAL CONTRACTION
- Aggressive Statin Therapy in Multicenter Trial and Effectiveness for the Reduction of Intra-myocardial Damage Caused by non-Q-wave Acute Coronary Syndrome(Acute Coronary Syndrome, Basic/Clinical 1 (IHD), The 69th Annual Scientific Meeting of the Japanese
- A Nation-Wide Survey on Indoor Radon from 2007 to 2010 in Japan
- PJ-254 Impact of statin treatment before percutaneous coronary intervention in patients who have acute coronary syndromes without ST-segment elevation(Acute Myocardial Infarction, Clinical (Diagnosis/Treatment) 11 (IHD) : PJ43)(Poster Session (Japanese))
- PJ-093 The Factors of Target Lesion Revascularization After Percutaneous Coronary Intervention for Left Main Coronary Artery(Coronary Revascularization, PTCA/Stent/DCA/Rotablator/New Device 3 (IHD) : PJ16)(Poster Session (Japanese))
- PE-059 Long Term Results of Pleotropic Effect on Statin Treatment to Lower LDL Patients with Non-ST Elevation Acute Coronary Syndrome(Acute Coronary Syndrome, Basic/Clinical 2 (IHD) : PE11)(Poster Session (English))
- OE-147 Primary Angioplasty under Distal Protection is More Effective to Improve Myocardial Perfusion in AMI Patients with high CRP value(Acute Myocardial Infarction, Clinical (Diagnosis/Treatment) 5 (IHD) : OE18)(Oral Presentation (English))
- -0535-EFFECT OF HYPOCHLOROUS ACID ON CALCIUM METABOLISM OF ISOLATED CARDIOMYOCYTES
- Ventricular Wall Motion and NE Release in Post-ischemic Reperfused Myocardium : 54th Annual Scientific Session of the Japanese Circulation Society
- -423-THE MECHANISM OF OXIDANT-INDUCED PERTURBATION OF CALCIUM HOMEOSTASIS : Myocardial Metabolism, Biochemistry : FREE COMMUNICATIONS(II) : PROCEEDINGS OF THE 53th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY
- -369-PRE-SYNAPTIC ALPHA-2 RECEPTOR IN POST ISCHEMIC REPERFUSED MYOCARDIUM : Ventricular Function : FREE COMMUNICATIONS(II) : PROCEEDINGS OF THE 53th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY
- Fusion of Paramecia by Means of Altered Electrofusion
- EFFECT OF LOCAL CARDIAC SYMPATHETIC DENERVATION ON REGIONAL CONTRACTION : Cardiac Function (II) : FREE COMMUNICATIONS (IV) : PROCEEDINGS OF THE 49th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY
- RESPONSE OF POST-ISCHEMIC MYOCARDIUM TO SYMPATHETIC STIMULATION : Relation to Local Norepinephrine Release
- IMMUNOELECTRON MICROSCOPIC STUDIES ON CREATINE KINASE M LOCALIZATION IN ISCHEMIC AND REPERFUSED DOG MYOCARDIUM
- -0887-IMMUNOELECTRON MICROSCOPIC STUDIES ON THE CREATINE KINASE RELEASE MECHANISM FROM ACUE ISCHEMIC MYOCARDIAL CELLS : THE 54th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY
- -562- EFFECT OF AGING ON CARDIOVASCULAR REGULATION DURING EXERCISE
- -195- DIMINISHED RESPONSE OF MYOCARDIUM TO SYMPATHETIC STIMULATION AFTER CORONARY REPERFUSION : Cardiac : FREE COMMUNICATIONS(I) : PROCEEDINGS OF THE 51th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY
- -152-RESPONSE OF MYOCARDIUM TO SYMPATHETIC STIMULATION AFTER CORONARY REPERFUSION
- CHANGES IN BIOCHEMICAL SUBSTANCE INDUCED BY REPERFUSION AFTER CORONARY OCCLUSION : EFFECT OF PROPRANOLOL : PROCEEDINGS OF THE 47th ANNUAL SCIENTIFIC MEETING OF THE JAPANESE CIRCULATION SOCIETY : Coronary Circulation
- CARDIOVASCULAR ADJUSTMENT TO EXERCISE IN THE AGED : Exercise Test : 46th Annual Scientific Meeting, Japanese Circulation Society
- Rotational Isomers and Molecular Structures of (E)-Propionaldehyde Oxime as Studied from Electron Diffraction and Microwave Spectroscopic Data
- Crossed-Beam Experiment for the Scattering of Low Energy Electrons from Gas Phase C_
- Parathyroid Hormone-related Protein in Breast Cancer Tissues: Relationship between Primary and Metastatic Sites
- Radioactive Concentration of Food Caused by Fukushima Nuclear Power Plant Disaster and New Radiological Standards for Foodstuffs in the Existing Exposure Situation in Japan after a Severe Nuclear Accident
- The microwave spectrum of acrylaldehyde oxime.
- The microwave spectrum of (Z)-(propionaldehyde oxime).
- Serial determinations of serum enzymes following Aorta-Coronary bypass surgery and acute myocardial infarction.
- The microwave spectra, dipole moments, and two isomers of cyclopentadiene-1-carbonitrile.
- Microwave spectrum of syn-acetaldehyde oxime-d.
- The microwave spectrum of 1-propanethiol.
- Microwave spectrum, barrier to internal rotation, and dipole moment of methyl selenocyanate.
- The microwave spectrum of anti-acetaldehyde oxime-d.
- Microwave Spectrum and Centrifugal Distortion Effects of Thionyl Fluoride
- Cardiovascular response to exercise in pacemaker implanted patients with fixed heart rate.
- Microwave spectrum, structure, and quadrupole coupling constant of S-cis o-chlorophenol-d.
- Microwave spectrum, structure, and quadrupole coupling constant of o-chlorophenol.
- Microwave spectrum and barrier to internal rotation of 4-chlorophenol.
- Guideline for Radiation Safety in Interventional Cardiology (JCS 2011) : Digest Version
- The microwave spectrum and molecular structure of methyl selenocyanate.
- Microwave spectrum of ethyl isothiocyanate.
- The microwave spectrum of ethyl isocyanate.
- The microwave spectrum of (Z)-(acrylaldehyde oxime).
- Smoking topography and biomarkers of exposure among Japanese smokers : associations with cigarette emissions obtained using machine smoking protocols
- Incidental focal FDG uptake in heart is a lighthouse for considering cardiac screening