Microwave spectrum, structure, and quadrupole coupling constant of o-chlorophenol.
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概要
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The microwave spectrum of <I>o</I>-chlorophenol has been observed in the frequency range 10–34 GHz. The rotational and centrifugal distortion constants were obtained for two isotopic species, <SUP>35</SUP>ClC<SUB>6</SUB>H<SUB>4</SUB>OH and <SUP>37</SUP>ClC<SUB>6</SUB>H<SUB>4</SUB>OH. The analysis of the hyperfine structure gives the following nuclear quadrupole coupling constants for <SUP>35</SUP>Cl species: χ<SUB>aa</SUB>=−67.6, χ<SUB>bb</SUB>=33.3, and χ<SUB>cc</SUB>=34.3 (MHz). The spectrum assigned has been attributed to the <I>cis</I>-form (intramolecularly hydrogen bonded between Cl and HO) from a brief consideration of the relative intensity of the a-and b- type transitions. No significant effect of the intramolecular hydrogen bonding on the nuclear quadrupole coupling was observed.
- 公益社団法人 日本化学会の論文
著者
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Yamaguchi Ichiro
Department Of Clinical Laboratory Yamagata University School Of Medicine
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Onda Masao
Department of Chemistry, Faculty of Science and Technology, Sophia University
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Oshima Yoshitomo
Department of Chemistry, Faculty of Science and Technology, Sophia University
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