Photochemistry of Non-enolizable β-Diketones Containing Cyclopropane Ring in Conjugation
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概要
- 論文の詳細を見る
Irradiation of bicyclo[3.1.0]hexane-2,4-diones affords isomeric enol lactones retaining the cyclopropane ring. In contrast, photoreaction of 6,6-dimethylspiro[2.5]octane-4,8-dione in ethanol results in the formation of an isomeric benzofuran derivative and dimedone-acetaldehyde condensation product. Cleavage of the cyclopropane ring is characteristic of the behavior of the latter β-diketone.
- 公益社団法人 日本化学会の論文
著者
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Nozaki Hitosi
Department of Industrial Chemistry, Faculty of Engineering Kyoto University
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Okada Taiiti
Department of Industrial Chemistry, Kyoto University
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Kawanisi Mituyosi
Department of Industrial Chemistry, Faculty of Engineering Kyoto University
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Kamogawa Koiti
Department of Industrial Chemistry, Kyoto University
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