The Photolysis and Thermolysis of Ethyl Azidoformate in the Presence of Ketones
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概要
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The photochemical decomposition of ethyl azidoformate (I) in an acetone solution gives the nitrene adduct, oxazirane II, whereas the thermolysis of the solution gives a C–H insertion product, III. The photolysis of I in cyclohexanone gives an α-insertion product, IX, while the thermolysis affords a β-insertion product, X, and an oxazole, XIII, in addition to IX. The multiplicity of the reactive species is examined in terms of the heavy-atom effect.
- 公益社団法人 日本化学会の論文
著者
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Hiyama Tamejiro
Department Of Marerial Chemistry Graduate School Of Engineering Kyoto University
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FUJITA Shinsaku
Department of Chemistry and Materials Technology, Kyoto Insititute of Technology
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Nozaki Hitosi
Department of Industrial Chemistry, Faculty of Engineering Kyoto University
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Taguchi Hiroaki
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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Hiyama Tamejiro
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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