Polyborylated reagents for modern organic synthesis
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概要
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Diverse kinds of gem- and vic-diborylated compounds are now readily available thanks to advances in gem-diborylation of lithium carbenoids as well as vic-diborylation of carbon–carbon multiple bonds with diboron compounds. These diborylated reagents lead to invention of polyborylated reagents and many novel and useful synthetic methods for supreme stereocontrol. This review summarizes preparative methods and synthetic reactions of di- and polyborylated reagents with the emphasis on multiple bond formation.(Communicated by Hitosi NOZAKI, M.J.A.)
- 日本学士院の論文
著者
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HIYAMA Tamejiro
Department of Material Chemistry, Graduate School of Engineering, Kyoto University
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Hiyama Tamejiro
Department Of Marerial Chemistry Graduate School Of Engineering Kyoto University
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Shimizu Masaki
Department Of Angiogenesis And Vascular Development School Of Medicine Kanazawa University
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