Synthesis of 2,5-dehydrohomoadamantane (tetracyclo[5.3.1.02,5.03,9]undecane) from 2,4-dehydrohomoadamantane (tetracyclo[5.3.1.03,5.04,9]undecane).
スポンサーリンク
概要
- 論文の詳細を見る
A reaction of 2,4-dehydrohomoadamantane with NBS in AcOH followed by LiAlH<SUB>4</SUB> reduction and subsequent CrO<SUB>3</SUB>–pyridine complex oxidation gave <I>endo</I>-2-bromohomoadamantan-4-one (<B>9</B>) in good yield. A treatment of <B>9</B> with <I>t</I>-BuOK in <I>t</I>-BuOH followed by Wolff-Kishner reduction furnished 2,5-dehydrohomoadamantane.
- 公益社団法人 日本化学会の論文
著者
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Yoshikawa Masato
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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Katsushima Takeo
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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Kawanisi Mituyosi
Department of Industrial Chemistry, Faculty of Engineering Kyoto University
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Yamagughi Ryohei
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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