Chromium(VI) or ruthenium(II) complex catalysis in oxidation of alcohols to aldehydes and ketones by means of bis(trimethylsilyl) peroxide.
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概要
- 論文の詳細を見る
Bis(trimethylsilyl) peroxide (BTSP) serves as an effective oxidant of alcohols in the presence of chromium(VI) or ruthenium(II) complexes as catalysts in dichloromethane. Selective oxidation of primary alcohols in preference to secondary ones using RuCl<SUB>2</SUB>(PPh<SUB>3</SUB>)<SUB>3</SUB> as a catalyst is also described.
- 公益社団法人 日本化学会の論文
著者
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Takai Kazuhiko
Department Of Applied Chemistry Faculty Of Engineering Okayama University
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Utimoto Kiitiro
Department Of Industrial Chemistry Faculty Of Engineering Kyoto University
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Nozaki Hitosi
Department of Industrial Chemistry, Faculty of Engineering Kyoto University
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Matsubara Seijiro
Department of Industrial Chemistry, Faculty of Engineering Kyoto University
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Oshima Koichiro
Department of Chemistry, Massachusetts Institute of Technology
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Kanemoto Shigekazu
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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