Sequential Introduction of Carbon Nucleophiles onto Silicon Atoms Using Methyl as a Leaving Group

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概要

• 論文の詳細を見る
• 2009-02-05

著者

• Horie Hiroaki

  Department Of Material Chemistry Graduate School Of Engineering Kyoto University

• MATSUBARA Seijiro

  Department of Material Chemistry, Kyoto University

• Matsubara Seijiro

  Department Of Material Chemistry Faculty Of Enginnering Kyoto University

• KAJITA Yuichi

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Kajita Yuichi

  Department Of Material Chemistry Graduate School Of Engineering Kyoto University

• Matsubara Seijiro

  Department of Industrial Chemistry, Faculty of Engineering Kyoto University

関連論文

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• Preparation of Deuterium Labelled Organophosphonium Salts (Wittig Salts) under Hydrothermal Condition Catalyzed by Molecular Sieves
• Ruthenium-catalyzed Isomerization of Alkenol into Alkanone in Water under Irradiation of Microwaves
• Allylation of Carbonyl Compounds with Allylic Gallium Reagents
• Carbazole Synthesis by Platinum-catalyzed C-H Functionalizing Reaction Using Water as Reoxidizing Reagent
• Preparation of Organoytterbium Reagent from Ytterbium Trichloride and Organomagnesium
• Preparation of Ester-group Substituted Allylic Zinc by Palladium-catalyzed Umpolung of γ-Acyloxy-α,β-unsaturated Ester by Bis(iodozincio)methane
• Nickel-catalyzed [4+2] Cycloaddition of Alkynes to Carbonylsalicylamides via Elimination of Isocyanates
• Ruthenium Catalyzed Deuterium Labelling of α-Carbon in Primary Alcohol and Primary/Secondary Amine in D_2O
• Palladium-Catalyzed H-D Exchange Reaction under Hydrothermal Condition
• S_N2 Type Hydrolysis of Secondary Alkyl Halides and Sulfonates in Hydrothermal Water
• Preparation and Reaction of Phenylsulfonyl-substituted Dizinciomethane
• Stereocontrolled Reduction of 2-Acyl-1,3-oxathiane Derivatives by Zn(BH_4)_2 and YCl_3-NaBH_4
• Sequential Introduction of Carbon Nucleophiles onto Silicon Atoms Using Methyl as a Leaving Group
• Bis(iodozincio)methane as a synthetic tool
• Samarium Diiodide-Mediated Reaction of Organic Halides with Carbonyl Compounds
• A Preparation of β-Oxoester Enolate Equivalents from SmI_2 and α-Bromoalkanoates
• Preparation of Dialkoxyborylbis(bromozincio)methane and Its Reaction with Electrophiles
• Preparation of Zinc-Homoenolate from α-Sulfonyloxy Ketone and Bis(iodozincio)methane
• Wittig Type Methylenation of Ketones with Bis(iodozincio)methane and Ionic Liquid
• The Rate Enhancement Effect of Protodesilylation of Arylsilane Derivatives
• Iron(II) Chloride-mediated Addition of Dialkylmagnesium to Carbonyl Compounds
• Fabrication of Nano-structure by Diels-Alder Reaction
• Nickel-catalyzed Decarbonylative Cycloaddition of Phthalic Anhydrides with 1,3-Dienes
• Nickel-catalyzed Cycloadditions of Benzoxazinones with Alkynes : Synthesis of Quinolines and Quinolones
• Wittig Like Methylenation of Aldehydes in a Microflow System: Selective Methylenation by Differential of Plural Reactions
• Methylenation of Esters with Bis(iodozincio)methane-TiCl_2-TMEDA System
• Nickel-catalyzed [3+2] Cycloaddition of α,β-Unsaturated Ketones with Vinyl Oxiranes
• Nickel-catalyzed Cycloaddition of Aromatic (O-Benzyl)ketoximes with Alkynes to Produce Isoquinoline and Isoquinoline N-Oxide Derivatives
• Nickel-catalyzed Heteroannulation of o-Haloanilines with Alkynes
• Nickel-catalyzed Decarboxylative Polymerization of 6-Alkynylisatoic Anhydride
• Rapid Preparation of Cycloheptane Ring from 1,2-Diketone and Bis(iodozincio)methane via Oxy-Cope Rearrangement Using Microflow System
• Isomerization of allylic alcohols catalyzed by vanadium or molybdenum complexes.
• Reformatsky type reaction with new aluminium reagents containing Al-Sn or Al-Pb linkage.
• New methods for the synthesis of 3(2H)-furanones and 2(5H)-furanones.
• Nickel-catalyzed Cycloaddition of α,β-Unsaturated Oximes with Alkynes : Synthesis of Highly Substituted Pyridine Derivatives
• Synthesis of homoallylic alcohols from allylic phosphates and aldehydes with organoaluminum reagent containing Al-Sn linkage.
• Baeyer-Villiger oxidation with Me3SiOOSiMe3 under assistance of SnCl4 or BF3OEt2.
• Chromium(VI) or ruthenium(II) complex catalysis in oxidation of alcohols to aldehydes and ketones by means of bis(trimethylsilyl) peroxide.
• Nickel-catalyzed Decarbonylative Polymerization of 5-Alkynylphthalimides : A New Methodology for the Preparation of Polyheterocycles
• Copper-catalyzed 1,4-Addition Reaction of Grignard Reagent to Enones Using Microflow System

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