S_N2 Type Hydrolysis of Secondary Alkyl Halides and Sulfonates in Hydrothermal Water

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概要

• 論文の詳細を見る
• 2004-07-05

著者

• MATSUBARA Seijiro

  Department of Material Chemistry, Kyoto University

• OSHIMA Koichiro

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Matsubara Seijiro

  Department Of Material Chemistry Graduate School Of Engineering Kyoto University

• Matsubara Seijiro

  Department Of Material Chemistry Faculty Of Enginnering Kyoto University

• Yamasaki Yuki

  Department Of Chemistry Faculty Of Economics Hosei University

• Yamasaki Y

  Department Of Industrial Chemistry Osaka Prefectural College Of Technology

• Oshima Koichiro

  Department Of Material Chemistry Graduate School Of Engineering Kyoto University

• HIRAYAMA Takaharu

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Hirayama Takaharu

  Department Of Material Chemistry Graduate School Of Engineering Kyoto University

• Oshima Koichiro

  Department Of Industrial Chemistry Faculty Of Engineering Kyoto University

• Matsubara Seijiro

  Department of Industrial Chemistry, Faculty of Engineering Kyoto University

• Oshima Koichiro

  Department of Chemistry, Massachusetts Institute of Technology

関連論文

• Fullerene and Sulfur Compounds
• Synthesis and characterization of bulky mesoporous silica Pd-MCM-41( Innovative Ceramic Materials and Technologies for Global Environmental Protection)
• Copper-Catalyzed Arylation of Chlorosilanes with Grignard Reagents
• Palladium-catalyzed Mizoroki-Heck Reactions of 2-Methylene-1,3-dithiane 1-Oxide with Aryl Iodides
• Synthesis of β,γ-Unsaturated Ketones from Acid Chlorides through Carbon-Pentamethylcyclopentadienyl Bond Formation and Cleavage
• Synthesis of Prenylarenes and Related (Multisubstituted Allyl)arenes from Aryl Halides and Homoallyl Alcohols via Palladium-Catalyzed Retro-Allylation
• Selectivity in Organic Group Transfer in Reactions of Mixed Diorganomanganese(II) and Triorganomanganate(II) with 2-Cyclohexen-1-one or Cyclohexanecarbaldehyde
• Manganese-Catalyzed Silylmagnesiation of Acetylenes and 1,3-Dienes
• Manganese-catalyzed Phenylation of Acetylenic Compounds with a Phenyl Grignard Reagent
• Preparation of Deuterium Labelled Organophosphonium Salts (Wittig Salts) under Hydrothermal Condition Catalyzed by Molecular Sieves
• Vanadium-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents
• Trialkylmanganate Mediated Radical Addition of Triphenylgermane to Carbon-Carbon Multiple Bonds
• Ruthenium-catalyzed Isomerization of Alkenol into Alkanone in Water under Irradiation of Microwaves
• Effects of Additives on Microstructures of Titanate Based Nanotubes Prepared by the Hydrothermal Process
• Synthesis of monolithic tobermorite from blast furnace slag and evaluation of its Pb removal ability
• Synthesis of Pt-Entrapped Titanate Nanotubes
• Radical Addition of α-Halo Ester to Homoallylic Gallium or Indium Species : Formation of Cyclopropane Derivatives
• Allylation of Carbonyl Compounds with Allylic Gallium Reagents
• Carbazole Synthesis by Platinum-catalyzed C-H Functionalizing Reaction Using Water as Reoxidizing Reagent
• Preparation of Organoytterbium Reagent from Ytterbium Trichloride and Organomagnesium
• Stereoselective Allylation of 3-Oxo Amides
• Preparation of Ester-group Substituted Allylic Zinc by Palladium-catalyzed Umpolung of γ-Acyloxy-α,β-unsaturated Ester by Bis(iodozincio)methane
• Nickel-catalyzed [4+2] Cycloaddition of Alkynes to Carbonylsalicylamides via Elimination of Isocyanates
• Ruthenium Catalyzed Deuterium Labelling of α-Carbon in Primary Alcohol and Primary/Secondary Amine in D_2O
• Palladium-Catalyzed H-D Exchange Reaction under Hydrothermal Condition
• Dechlorination of Concentrated Monochloroalkanes under Various Hydrothermal Conditions
• NMR Study of Hydrothermal Reactions of Dichloromethance with and without Alkali
• Synthesis of Dense and Pinhole-free Y-zeolite for Separation Membrane Using a Modified Hydrothermal Method
• S_N2 Type Hydrolysis of Secondary Alkyl Halides and Sulfonates in Hydrothermal Water
• Synthesis of Coordinatively Unsaturated Cobalt(II)-Alkyl Complexes Bearing Phosphorus-bridged [1.1]Ferrocenophanes
• Preparation and Reaction of Phenylsulfonyl-substituted Dizinciomethane
• Facile Preparation of Vicinal Allylsiloxy-and Vinylsiloxyhaloalkanes and Their Radical Cyclization Reaction
• Ytterbium Catalyzed Oxidation of Alcohols to Aldehydes and Ketones by Means of Iodosylbenzene
• Tris(trimethylsilyl)silyl Radical Induced Bicyclization of 1,6-Dienes and 1,6-Enynes Providing 3,3-Bis(trimethylsilyl)-3-silabicyclo[3.3.0]octanes and 3-Silabicyclo[3.3.0]oct-1-enes
• Stereocontrolled Reduction of 2-Acyl-1,3-oxathiane Derivatives by Zn(BH_4)_2 and YCl_3-NaBH_4
• 2-Lithio-2-trimethylsilyl-1-silacyclopentane as a Synthetic Equivalent of 1-Lithio-1,4-butanediol
• Radical Addition of Polyhaloalkanes to 2-Ethynyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Radical Addition of Alkyl Halides to 2-Methylene-1,3-dithiane Monoxide as a Ketene Equivalent
• Extended Pummerer Reaction of Arylketene Dithioacetal Monoxides with Aromatic Compounds by Means Trifluoromethanesulfonic Anhydride
• Triethylborane-Induced Radical Reaction of Alkynylgallium with α-Halo Carbonyl Compounds
• Triethylborane Induced Radical Reaction of Gallium Enolates with α-Halo Esters
• Tributylmanganate(II)-Mediated Cyclization of Enynes
• Sequential Introduction of Carbon Nucleophiles onto Silicon Atoms Using Methyl as a Leaving Group
• Bis(iodozincio)methane as a synthetic tool
• Samarium Diiodide-Mediated Reaction of Organic Halides with Carbonyl Compounds
• A Preparation of β-Oxoester Enolate Equivalents from SmI_2 and α-Bromoalkanoates
• Preparation of Dialkoxyborylbis(bromozincio)methane and Its Reaction with Electrophiles
• Preparation of Zinc-Homoenolate from α-Sulfonyloxy Ketone and Bis(iodozincio)methane
• Wittig Type Methylenation of Ketones with Bis(iodozincio)methane and Ionic Liquid
• The Rate Enhancement Effect of Protodesilylation of Arylsilane Derivatives
• Iron(II) Chloride-mediated Addition of Dialkylmagnesium to Carbonyl Compounds
• Fabrication of Nano-structure by Diels-Alder Reaction
• Synthesis of Pyrimidines via Base-induced Condensation of α-Chloro Oxime Derivatives
• Cobalt-catalyzed Cross-coupling Reactions of Aryl Bromides with Alkyl Grignard Reagents
• Regio- and Stereoselective Additions of Diphenyldithiophosphinic Acid to N-(1-Alkynyl)amides and 1-Alkynyl Sulfides
• Silylcupration and Copper-Catalyzed Carbomagnesiation of Ynamides : Application to Aza-Claisen Rearrangement
• Regio- and Stereoselective Hydrothiolation Reactions of Ynamides with Diphenyldithiophosphinic Acid : Straightforward Synthesis of Ketene N,S-Acetal Derivatives
• Transformations of N-Allyl-N-(phenylethynyl)arenesulfonamides into 2,2-Disubstituted 4-Pentenenitriles through Aza-Claisen Rearrangement that Follows Carbomagnesiation
• Cobalt-Catalyzed Allylzincations of Internal Alkynes
• Radical Cyclization of Allyl 2-Iodophenyl Ether,N,N-Diallyl-2-iodoaniline, and 2-Iodoethanal Acetal by Means of Trialkylmanganate(II)
• Syntheses and Characterization of Bulky Mesoporous Silica MCM-41 by Hydrothermal Hot-Pressing Method
• Rhodium-Catalyzed Reaction of 1-Alkynylphosphines with Water Yielding (E)-1-Alkenylphosphine Oxides
• Atom-transfer Radical Addition of α-Iodo Esters to 1-Alkynyl Sulfides
• Palladium-Catalyzed 1-Methylene-2-propenylation Reactions of Aryl Bromides with 3,4-Alkadien-1-ols via Carbon-Carbon Bond Cleavage for the Synthesis of 2-Aryl-1,3-butadiene Derivatives
• Efficient Aerobic Oxidation of Phosphines, Phosphites, and Sulfides by Using Trialkylborane
• Copper-Catalyzed Allylation of Alkyl Halides with Allylic Grignard Reagents
• Development of Radical Reactions with Zirconocene Complexes as Electron Transfer Reagents
• Nickel-catalyzed Carbometalation Reactions of [2-(1-Propynyl)phenyl]methanol with 1-Alkenylmagnesium Reagents
• Cobalt-catalyzed Cross-coupling Reaction of Chloropyridines with Grignard Reagents
• Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenes with a Water-Soluble Radical Initiator Initiator in Aqueous Media: Facile Synthesis of γ-Lactones
• Reduction of Organic Halides with Tri-2-furylgermane: Stoichiometric and Catalytic Reduction
• Radical Cyclization of N-Allyl-2-halo Amide in Water
• Radical Cyclization Reaction Using a Combination of Phosphinic Acid and a Base in Aqueous Ethanol
• Three-step α-Acylation of (E)-Cinnamate Esters with Inversion of Stereochemistry through Formation and Cleavage of Carbon-Pentamethylcyclopentadienyl Bonds
• Metal-Mediated Retro-Allylation of Homoallyl Alcohols for Highly Selective Organic Synthesis
• Cobalt-Catalyzed Allylic Substitution Reaction of Allylic Ethers with Phenyl and Trimethylsilylmethyl Grignard Reagents
• Highly Selective Synthetic Reactions by the Combined Use of Organometallic Reagents and Radical Species
• Triethylborane-Induced Radical Reactions in Ionic Liquids
• Stereoselective Reduction of α,β-Epoxy Ketones into erythro-α,β-Epoxy Alcohols with Sodium Borohydride in the Presence of Calcium Chloride
• Manganese (II) Chloride-Catalyzed Alkylmagnesation of 2-Alkynylphenol
• Reaction of 1, 3-Dihalopropene with Trialkylmanganate
• Nickel-catalyzed Decarbonylative Cycloaddition of Phthalic Anhydrides with 1,3-Dienes
• Nickel-catalyzed Cycloadditions of Benzoxazinones with Alkynes : Synthesis of Quinolines and Quinolones
• Wittig Like Methylenation of Aldehydes in a Microflow System: Selective Methylenation by Differential of Plural Reactions
• Methylenation of Esters with Bis(iodozincio)methane-TiCl_2-TMEDA System
• A Facile Synthesis of 1,1-Disilylethenes via Me_3MgLi-Induced Monomethylation of Dibromodisilylmethanes
• Reaction of Trialkyl(dibromomethyl)silanes or 1,2-Bis(dibromomethyl)benzene with Triorganomanganates. A Facile and Selective Synthesis of Alkenylsilanes and 1,2-Diaryl-1,2-dihydrobenzocyclobutenes
• Radical Reaction by a Combination of Phosphinic Acid and a Base in Aqueous Media
• Nickel-catalyzed [3+2] Cycloaddition of α,β-Unsaturated Ketones with Vinyl Oxiranes
• Bis(cyclopentadienyldicarbonyliron) as a Convenient Carbon Monoxide Source in Palladium-catalyzed Carbonylative Coupling of Aryl Iodides with Amines, Alcohols, and Thiols
• Nickel-catalyzed Cycloaddition of Aromatic (O-Benzyl)ketoximes with Alkynes to Produce Isoquinoline and Isoquinoline N-Oxide Derivatives
• Nickel-catalyzed Heteroannulation of o-Haloanilines with Alkynes
• Nickel-catalyzed Decarboxylative Polymerization of 6-Alkynylisatoic Anhydride
• Rapid Preparation of Cycloheptane Ring from 1,2-Diketone and Bis(iodozincio)methane via Oxy-Cope Rearrangement Using Microflow System
• Triethylborane-induced hydrodehalogenation of organic halides by tin hydrides.
• Palladium Catalyzed Reaction of Silacyclobutanes with Acetylenes.
• The Reduction of gem-Dibromocyclopropanes by Means of Chromium(II) Acetate or Potassium Pentacyanocobaltate
• Cross-coupling reaction between enol phosphates and organoaluminium compounds in the presence of palladium(0) catalyst.
• Isomerization of allylic alcohols catalyzed by vanadium or molybdenum complexes.
• Synthesis of Pt-Entrapped Titanate Nanotubes

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