Trialkylmanganate Mediated Radical Addition of Triphenylgermane to Carbon-Carbon Multiple Bonds

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概要

• 論文の詳細を見る
• 2000-09-15

著者

• OSHIMA Koichiro

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• KINOSHITA Hidenori

  Department of Emergency and Critical Care Medicine, Niigata University Faculty of Medicine

• Kinoshita Hidenori

  Department Of Material Chemistry Graduate School Of Engineering Kyoto University

• KAKIYA Hirotada

  Department of Material Chemistry, Graduate School of Engineering, Kyoto University

• Kakiya Hirotada

  Department Of Material Chemistry Graduate School Of Engineering Kyoto University

• Kinoshita Hidenori

  Department Of Applied Chemistry Graduate School Of Science And Engineering Saitama University

• Oshima Koichiro

  Department Of Industrial Chemistry Faculty Of Engineering Kyoto University

• Oshima Koichiro

  Department of Chemistry, Massachusetts Institute of Technology

関連論文

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• Synthesis of β,γ-Unsaturated Ketones from Acid Chlorides through Carbon-Pentamethylcyclopentadienyl Bond Formation and Cleavage
• Synthesis of Prenylarenes and Related (Multisubstituted Allyl)arenes from Aryl Halides and Homoallyl Alcohols via Palladium-Catalyzed Retro-Allylation
• Selectivity in Organic Group Transfer in Reactions of Mixed Diorganomanganese(II) and Triorganomanganate(II) with 2-Cyclohexen-1-one or Cyclohexanecarbaldehyde
• Manganese-Catalyzed Silylmagnesiation of Acetylenes and 1,3-Dienes
• Manganese-catalyzed Phenylation of Acetylenic Compounds with a Phenyl Grignard Reagent
• Preparation of Deuterium Labelled Organophosphonium Salts (Wittig Salts) under Hydrothermal Condition Catalyzed by Molecular Sieves
• A case of a traumatic abdominal wall hernia that could not be identified until exploratory laparoscopy was performed
• Vanadium-Catalyzed Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents
• Trialkylmanganate Mediated Radical Addition of Triphenylgermane to Carbon-Carbon Multiple Bonds
• Ruthenium-catalyzed Isomerization of Alkenol into Alkanone in Water under Irradiation of Microwaves
• Radical Addition of α-Halo Ester to Homoallylic Gallium or Indium Species : Formation of Cyclopropane Derivatives
• Allylation of Carbonyl Compounds with Allylic Gallium Reagents
• Preparation of Organoytterbium Reagent from Ytterbium Trichloride and Organomagnesium
• Stereoselective Allylation of 3-Oxo Amides
• Ruthenium Catalyzed Deuterium Labelling of α-Carbon in Primary Alcohol and Primary/Secondary Amine in D_2O
• Palladium-Catalyzed H-D Exchange Reaction under Hydrothermal Condition
• Indium(III)-catalyzed Coupling between Alkynes and Aldehydes to α,β-Unsaturated Ketones
• S_N2 Type Hydrolysis of Secondary Alkyl Halides and Sulfonates in Hydrothermal Water
• Platinum(II)-catalyzed Acetal-Ene Reaction : Easy Access to Homoallylic Ethers
• Synthesis of Coordinatively Unsaturated Cobalt(II)-Alkyl Complexes Bearing Phosphorus-bridged [1.1]Ferrocenophanes
• Facile Preparation of Vicinal Allylsiloxy-and Vinylsiloxyhaloalkanes and Their Radical Cyclization Reaction
• Ytterbium Catalyzed Oxidation of Alcohols to Aldehydes and Ketones by Means of Iodosylbenzene
• Tris(trimethylsilyl)silyl Radical Induced Bicyclization of 1,6-Dienes and 1,6-Enynes Providing 3,3-Bis(trimethylsilyl)-3-silabicyclo[3.3.0]octanes and 3-Silabicyclo[3.3.0]oct-1-enes
• 2-Lithio-2-trimethylsilyl-1-silacyclopentane as a Synthetic Equivalent of 1-Lithio-1,4-butanediol
• Radical Addition of Polyhaloalkanes to 2-Ethynyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Radical Addition of Alkyl Halides to 2-Methylene-1,3-dithiane Monoxide as a Ketene Equivalent
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• Bis(iodozincio)methane as a synthetic tool
• Wittig Type Methylenation of Ketones with Bis(iodozincio)methane and Ionic Liquid
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• Synthesis of Pyrimidines via Base-induced Condensation of α-Chloro Oxime Derivatives
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• Silylcupration and Copper-Catalyzed Carbomagnesiation of Ynamides : Application to Aza-Claisen Rearrangement
• Regio- and Stereoselective Hydrothiolation Reactions of Ynamides with Diphenyldithiophosphinic Acid : Straightforward Synthesis of Ketene N,S-Acetal Derivatives
• Transformations of N-Allyl-N-(phenylethynyl)arenesulfonamides into 2,2-Disubstituted 4-Pentenenitriles through Aza-Claisen Rearrangement that Follows Carbomagnesiation
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• Radical Cyclization of Allyl 2-Iodophenyl Ether,N,N-Diallyl-2-iodoaniline, and 2-Iodoethanal Acetal by Means of Trialkylmanganate(II)
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• Development of Radical Reactions with Zirconocene Complexes as Electron Transfer Reagents
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• Radical Addition of 2-Iodoalkanamide or 2-Iodoalkanoic Acid to Alkenes with a Water-Soluble Radical Initiator Initiator in Aqueous Media: Facile Synthesis of γ-Lactones
• Reduction of Organic Halides with Tri-2-furylgermane: Stoichiometric and Catalytic Reduction
• Radical Cyclization of N-Allyl-2-halo Amide in Water
• Radical Cyclization Reaction Using a Combination of Phosphinic Acid and a Base in Aqueous Ethanol
• Three-step α-Acylation of (E)-Cinnamate Esters with Inversion of Stereochemistry through Formation and Cleavage of Carbon-Pentamethylcyclopentadienyl Bonds
• Metal-Mediated Retro-Allylation of Homoallyl Alcohols for Highly Selective Organic Synthesis
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• Isomerization of allylic alcohols catalyzed by vanadium or molybdenum complexes.
• Reformatsky type reaction with new aluminium reagents containing Al-Sn or Al-Pb linkage.
• New methods for the synthesis of 3(2H)-furanones and 2(5H)-furanones.
• Palladium catalyzed hydrostannylation and hydrogermylation of acetylenes.
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• Carbocyclic ring formation by the intramolecular reaction between enol silyl ether and allylic acetate moieties.
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• The Reaction of O,O′-Diethyl α-Lithiomethylphosphonate with Organic Dihalides
• Triethylborane Induced Perfluoroalkylation of Silyl Enol Ethers and Ketene Silyl Acetals with Perfluoroalkyl Iodides.
• Rearrangement of vic-diol monoacetates promoted by organoaluminium compounds.
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• Chromium(VI) or ruthenium(II) complex catalysis in oxidation of alcohols to aldehydes and ketones by means of bis(trimethylsilyl) peroxide.
• Aliphatic Claisen rearrangement promoted by organoaluminium reagents.
• Cr(III) or Ce(IV) impregnated perfluorinated resin-sulfonic acid catalyst for the oxidation of alcohols.
• Palladium-catalyzed ketone synthesis from acyl chloride and organoaluminum reagents.
• Preparation of 2-alkenylsilanes and 2-alkenylstannanes by the reaction of 2-alkenyl-1,1-cyclopropanedicarboxylate esters with PhMe2SiAlEt2 and (Ph3Sn)2Zn. Generation of 2-alkenyl-3-cyclopentene-1,1-decarboxylates via alkenyl-substituted .PI.-allylpalladiu

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