Preparation and Thermal Decomposition of Acyl Carbamoyl Peroxides

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概要

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• Thirteen acyl carbamoyl peroxides, a new class of peroxides, were prepared by addition of peroxy-acids to organic isocyanates and their properties were examined. The thermal decompositions, especially of benzoyl <I>N</I>-(<I>p</I>-nitrophenyl) carbamoyl peroxide and benzoyl <I>N</I>-benzoylcarbamoyl peroxide, were studied in crystalline state and in solution, and it was shown that they decompose via three different mechanisms, involving either an amino-radical, a nitrene or a protonated nitrene, depending on reaction conditions.

• 公益社団法人 日本化学会の論文

著者

• Okazaki Renji

  Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University

• Simamura Osamu

  Department of Chemistry Faculty of Science The University of Tokyo

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