Influence of Substituent Groups on Nuclear Reactivity in the Formation of Substituted Biphenyls by Reaction of Aromatic Diazo and Related Compounds with Aromatic Liquids. V. Phenylation of Nitrobenzene and Anisole
スポンサーリンク
概要
- 論文の詳細を見る
<I>N</I>-Nitrosoacet(anilide-<SUP>14</SUP>C) has been decomposed at 20°C in a mixture of benzene with nitrobenzene or with anisole, and the reaction products have been analyzed for biphenyl and isomeric nitrobiphenyls or isomeric methoxybiphenyls by isotope dilution method. From these results the partial rate factors for the phenylation have been calculated to be for nitrobenzene: <I>o</I>, 9.38; <I>m</I>, 1.16; and <I>p</I>, 9.05; and for anisole: <I>o</I>, 3.56; <I>m</I>, 0.93; and <I>p</I>, 1.29.
- 社団法人 日本化学会の論文
著者
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Inukai Takashi
Department of Chemistry Faculty of Science The University of Tokyo
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Simamura Osamu
Department of Chemistry Faculty of Science The University of Tokyo
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Kobayashi Katsumi
Department of Chemistry Faculty of Science The University of Tokyo
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Inukai T.
Department of Chemistry Faculty of Science The University of Tokyo
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