Phosphinidenes and Related Intermediates. III. Reactions of Phosphinylidenes and Phosphinothioylidenes with Conjugated Dienes
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概要
- 論文の詳細を見る
Phenylphosphonic and phenylphosphonothioic dichlorides were dechlorinated with magnesium to generate phenylphosphinylidene and phenylphosphinothioylidene, respectively, in the presence of several 1,3-dienes. Reactions of phenylphosphinothioylidene with 2,3-dimethylbutadiene and 1,3-cyclohexadiene gave Diels-Alder type reaction products, that is, 3,6-dihydro-1,2-thiaphosphorin derivatives (<B>5</B> and <B>6</B>) and 6-phenyl-5,6-thiaphosphabicyclo[2.2.2]oct-2-ene 6-sulfide (<B>14</B>), respectively. Reaction of 2,3-diphenylbutadiene with phenylphosphinothioylidene afforded 1,2,4,5-tetraphenyl-1,2,3,6-tetrahydro-1,2-diphosphorin 1,2-disulfide (<B>10</B>), whereas that with phenylphosphinylidene gave 1,3,4-triphenyl-3-phospholene 1-oxide (<B>12</B>). The differences of these reactions have been discussed.
- 公益社団法人 日本化学会の論文
著者
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Inamoto Naoki
Department Of Chemistry Graduate School Of Science The University Of Tokyo
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Yoshifuji Masaaki
Department Of Chemistry Faculty Of Science Tohoku University
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Okazaki Renji
Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University
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Nakayama Shigenobu
Department Of Laboratory Animal Science Kitasato University School Of Medicine
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Inamoto Naoki
Department of Chemistry, Faculty of Science, The University of Tokyo
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Nakayama Shigenobu
Department of Chemistry, Faculty of Science, The University of Tokyo
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Inamoto Naoki
Department of Chemistry and Research Centre for Spectrochemistry, Faculty of Science, The University of Tokyo
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