Reaction of Dichlorotriphenylphosphorane with Bis(trimethylsilyl) Peroxide. A New Method for the Formation of Electrophilic Chlorine Source.
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概要
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Reactions of dichlorotriphenylphosphorane with bis(trimethylsilyl) peroxide in the presence of some organic compounds have been found to give chlorinated products. Aromatic hydrocarbons bearing electron-donating substituents give the corresponding monochloroarenes, while an enol silyl ether is converted into α-chloro ketone. The mechanism is briefly discussed.
- 公益社団法人 日本化学会の論文
著者
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Inamoto Naoki
Department Of Chemistry Graduate School Of Science The University Of Tokyo
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Okazaki Renji
Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University
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Tokitoh Norihiro
Department Of Chemistry Graduate School Of Science The University Of Tokyo
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Shibata Kazusato
Department of Chemistry, Faculty of Science, The University of Tokyo
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Itoh Yukinori
Department of Chemistry, Faculty of Science, The University of Tokyo
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