Chemistry of Nitrosoimines. VI. Attempted Syntheses of Some Resonance Stabilized Nitrosoimines and Their UV Spectra

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概要

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• 1,1,3,3-Tetrasubstituted 2-nitrosoguanidines, the attempted syntheses and UV spectra of which are reported, are unstable, and decomposed into the corresponding ureas and nitrogen, only 2-nitroso-1,1,3,3-tetraphenylguanidine (<B>1f</B>) being obtained as a pure compound. The reaction of <B>1f</B> with phenyl isocyanate gave pentaphenylguanidine, probably through 1,4-cycloaddition.

• 公益社団法人 日本化学会の論文

著者

• Akiba Kin-ya

  Department Of Chemistry Faculty Of Science Hiroshima University

• Inamoto Naoki

  Department Of Chemistry Graduate School Of Science The University Of Tokyo

• Matsunami Satoru

  Department of Chemistry, Faculty of Science, The University of Tokyo

• Eguchi Chikahiko

  Department of Chemistry, Faculty of Science, The University of Tokyo

• Inamoto Naoki

  Department of Chemistry and Research Centre for Spectrochemistry, Faculty of Science, The University of Tokyo

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