Metal phosphinylides and phosphinothioylides. VI. Some observations in reactions of diphenylphosphinic cloride with tetrahydrofuran in the presence of metal chlorides.
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概要
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<SUP>31</SUP>P-NMR data showed a formation of a stable 1 : 1 complex between diphenylphosphinic chloride (<B>1</B>) and aluminum chloride. The effect of common chloride ion on the reaction of <B>1</B> with tetrahydrofuran in the presence of zinc or cuprous chloride supported a cationic mechanism in the former case, and no free radical but homolytic mechanism in the latter.
- 公益社団法人 日本化学会の論文
著者
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Goda Koshiro
Department of Chemistry, Faculty of Science, The University of Tokyo
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Inamoto Naoki
Department of Chemistry and Research Centre for Spectrochemistry, Faculty of Science, The University of Tokyo
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