Photolytic and Thermal Decompositions of 5-Substituted 1,2,3,4-Thiatriazoles in the Presence of Olefins. Reactions of Sulfur Atoms
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概要
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Photochemical decompositions of 5-phenyl- and 5-amino-1,2,3,4-thiatriazoles in the presence of cyclohexene or tetramethylethylene led to the formation of the corresponding episulfide, the production of which has been explained in terms of sulfur atom reactions with the olefins. Kinetic measurements revealed the limitation of the reactions as a synthetic method of an episulfide from an olefin. Mechanism of the episulfide formation was briefly discussed. Thermal decompositions of these thiatriazoles in the presence of olefins gave rise to no episulfides.
- 公益社団法人 日本化学会の論文
著者
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Inamoto Naoki
Department Of Chemistry Graduate School Of Science The University Of Tokyo
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Okazaki Renji
Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University
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Okawa Kazumi
Department of Chemistry, Faculty of Science, The University of Tokyo
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Wajiki Seiji
Department of Chemistry, Faculty of Science, The University of Tokyo
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Inamoto Naoki
Department of Chemistry and Research Centre for Spectrochemistry, Faculty of Science, The University of Tokyo
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