The First Stable Aromatic S-Nitrosothiol: Synthesis, Structure and Reactivity

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概要

• 論文の詳細を見る
• 2001-12-05

著者

• TAKEDA Nobuhiro

  Institute for Chemical Research, Kyoto University

• TOKITOH Norihiro

  Institute for Chemical Research, Kyoto University

• OKAZAKI Renji

  Department of Chemistry, Graduate School of Science, The University of Tokyo

• Okazaki R

  Department Of Chemistry Graduate School Of Science The University Of Tokyo

• Okazaki Renji

  Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University

• Takeda Nobuhiro

  Institute For Chemical Research Kyoto University

• ITOH Maiko

  Department of Chemical and Biological Sciences, Faculty of Science, Japan Women's University

• TAKENAKA Keiko

  Department of Chemical and Biological Sciences, Faculty of Science, Japan Women's University

• Tokitoh Norihiro

  Institute For Chemical Research Kyoto University

• Nobuhiro Takeda

  Institute For Chemical Research Kyoto University

• Itoh Maiko

  Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University

• Takenaka Keiko

  Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University

• Okazaki R

  Univ. Tokyo Tokyo

関連論文

• Unexpected formation of dihydrobenzosilole derivative via the intramolecular cyclization in the reaction of overcrowded dichloromethylsilane with aryllithium
• Systematic Studies on Redox Behavior of Homonuclear Double-bond Compounds of Heavier Group 15 Elements
• Syntheses, Structures and Properties of Kinetically Stabilized Distibenes and Dibismuthenes, Novel Doubly Bonded Systems between Heavier Group 15 Elements
• Reaction of a Stable Silylene-Isocyanide Complex with Nitrile Oxides:A New Approach to the Generation of a Silanone
• The Chemistry of Germanium-Containing Heavy ketones
• Formantion and Reactions of the First Diarylgermanone Stable in Solution
• Thermal Retrocycloaddition of Overcrowded Germirenes. A New Method for the Generation of Gerdmylenes
• Reaction of Stable Sulfenic and Selenenic Acids Containing a Bowl-type Steric Protection Group with a Phosphine. Elucidation of the Mechanism of Reduction of Sulfenic and Selenenic Acids
• Structural Elucidation of 1,3-Phenylenebis(methylene)-Bridged Calix[6]arenes with Four Uncapped Hydroxy Groups
• Different Aggregating Properties of Two Conformationally Frozen Isomers of a Water-Soluble Bridged Calix[6]arene
• The Olefin Synthesis from β-Hydroxyalkylphosphonates Induced by Fluorides or Relatively Weak Bases
• Cycloaddition and Oxidation Reactions of a Stable Thioaldehyde, (2,4,6-Tri-t-butyl)thiobenzaldehyde
• Synthesis, Stereochemistry, and Thermolysis of β-Aminoalkylboranes
• Thermolysis of β-Siloxyalkylboranes: Formation of Alkenes and/or Silyl Enol Ethers
• Reactions of (2,4,6-Tri-t-butyl) thiobenzaldehyde with Diazo Compounds. Synthesis and Reactions of Sterically Congested Thiiranes
• Structure and Thermolysis of a 1,4,2-Oxatellurazole, a Novel Tellurium Containing Heterocycle
• Reaction of 2,4,6-Tri-t-butylselenobenzaldehyde with Sterically Crowded Diazo Compounds. Formation of Seleniranes
• Synthesis of Δ^3 -1,3,4 -Telluradiazolines, a Novel Tellurium - Containing Heterocycle
• The Phospha-Cope Rearrangement of 3-Phospha-1,5-hexadiene Derivatives Bearing a Hydroxyl Group
• Synthesis and Unusual Photochemical Reaction of Highly Congested 2,4,6-Tri-t-butylstyrene Episulfides
• Synthesis of Stable cis-Dichloro- and cis-Dimethylplatinum(II) Complexes Bearing Bulky Primary Phosphines and Introduction of an Alkyl Group on the Primary Phosphine Ligand
• Synthesis and Structure of a Kinetically Stabilized Stannanethione
• The First Examples of Stable Benzenes Fused with Two Three-membered Rings : Synthesis and Structures of the Two Stereoisomers of Bis(silacyclopropa)benzenes
• Intramolecular Si-C and C-H bond activation in a platinum complex leading to the formation of the platinacycles
• Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives
• Kinetically Stabilized 1,1'-Bis[(E)-diphosphenyl]ferrocenes : Syntheses, Structures, Properties, and Reactivity
• Synthesis and Properties of 9-Anthryldiphosphene
• Syntheses, Structures, and Properties of the First Stable 1,1'-Bis(diphosphenyl)ferrocenes
• Synthesis and Reactions of the First Stable 1-Germaallene
• The First Spectroscopic Observation of an Equilibrium between a Digermene and Germylenes and Experimental Determination of a Bond Dissociation Energy of a Ge-Ge Double Bond
• Oxidation and Thermolysis of a Stable Germaketenedithioacetal Derivative
• Control Factors of Two Reaction Modes of Pentacoordinate 1,2-Oxasiletanides, the Peterson Reaction and Homo-Brook Rearrangement
• Chalcogenation Reactions of Overcrowded Doubly Bonded Systems between Heavier Group 15 Elements
• Reaction of an Overcrowded Distibene with Elemental Sulfur and Crystallographic Analysis of the Sulfurization Products
• Kinetic Deuterium Isotope Effect in Single-Electron Transfer Occurring from Tributylphosphine to Viologens
• Reaction of Stable Silylene-Isocyanide Complexes with Boranes: Synthesis and Properties of the First Stablr Silylborane-Isocyanide Complexes
• Mechanistic Investigation of the Hydration Reaction of [Cr(η^6-silabenzene)(CO)_3] : Hydrido(silacyclohexadienyl)chromium Complex as an Intermediate
• Synthesis and Properties of Stable 1,2-Bis(metallocenyl)disilenes : Novel d-π Conjugated Systems with a Si=Si Double Bond
• Micropolarity around a Zwitterionic Solvatochrome Covalently Fixed in the Cavity of Bowl-Shaped Cyclophanes
• Synthesis of Novel Water-soluble Molecular Bowls and Their Unique Complexing Behavior with 1-Anilinonaphthalene-8-sulfonate
• Isolation of Two Conformationally Frozen Isomers of a Bridged Calix[6]arene
• Synthesis and Thermolysis of Tetracoordinate 1,2-Oxaphosphetanes Stabilized by Steric Protection
• Synthesis of Optically Active Phosphorus Compounds via Metal Phosphinites Generated by Reaction of Optically Active Selenophosphinates with Phenyllithium
• Novel Intermolecular Cyclization Reaction Involving a Thionitroso Group : Formation of a 3,3a-Dihydro-2,1-benzisothiazole from an o-Alkylthionitrosoarene
• Synthesis of Kinetically Stabilized Silaneselone and Silanetellone
• The First Stable Aromatic S-Nitrosothiol: Synthesis, Structure and Reactivity
• The First Chemical Trapping of Stibinidene,a Monovalent Antimony Compound
• Separation of Orientational Disorder in the X-Ray Analysis of the Kinetically Stabilized 2-Silanaphthalene
• Generation and Reactions of an Overcrowded Diaryldilithiosilane
• Synthesis, Structure, and Reactivity of Kinetically Stabilized Low-coordinated Organolead Compounds
• Synthesis of the First Stable Selenadistibirane and Its Molecular Structure
• An Unexpected Elimination of Cyclopentadienide Anion in the Reaction of Silacyclohexadienes with a Bulky Aryllithium
• Biscyanines Linked by a 1,8-Naphthylene Skeleton : Models of Polymethine Dye Aggregates
• Linear and Stack Oligostreptocyanines. Effects of Relative Orientation of Chromophores on Redox Potentials of Dye Aggregates
• Syntheses and Crystal Structures of Novel Antimony-Containing Cyclic Polysulfides^1
• A Monomeric, Donor-free Lithium Complex with a New Overcrowded β-Diketiminato Ligand
• Reactions of 2-Germanaphthalene with Elemental Sulfur and Selenium : Synthesis of Novel Cyclic Polychalcogenides Containing a Germanium, Trichalcogenagermolanes
• Synthesis and Spectroscopic Properties of Novel Silacyclic Compounds Containing a Titanium and Some Chalcogen Atoms
• Generation of 9-Stannaphenanthrene and Its Reactivities
• Synthesis of Kinetically Stabilized 1-Silanaphthalenes and Their Properties
• Generation of 1, 6-Disilahexapentaene in the Reduction of an Overcrowded Bis(bromodiaryl)butadiyne Leading to the Unexpected Formation of 2-Allenyl-1-benzosilole
• Synthesis, Structure, and Properties of the First Disulfur and Diselenium Complexes of Platinum
• Unusual Oxidation of Dichalcogenido Complexes of Platinum
• Thermal Dissociation of Disilenes into Silylenes
• Formation of a Unique Fluorosilene-KF Complex Bearing Bulky Substituents
• A New Method for the Synthesis of Stannylenes : Exhaustive Desulfurization of Tetrathiastannolanes
• Unusual Oxidation Reaction of an Overcrowded Thiagermacyclohexene Derivative
• Deprotonation of Aryl Methanedithioate by Lithium Amides : Formation of Lithium Arylthio(thioxo)methanide Having Unique Reactivity
• Evidence for Spiro-Conjugation in Perpendicularly-Linked Pentamethinestreptocyanine Diners
• Synthesis and Reactions of the First Lead-Sulfur Double-Bond Compounds, Plumbanethiones
• Synthesis and Structure of a Novel Cyclic Polysulfide, 2,4,6-Tris[bis(trimethylsilyl)methyl]phenyloctathionane
• 1,2,3,4,5,6,7,8-Octathionane, a Novel Cyclic Polysulfide. Synthesis and Crystal Structure
• Reaction of Tetrachalcogenastannolanes with Triphenylphosphine. A Novel Mode of Generation for Overcrowded Stannanethiones and Stannaneselones
• An ab initio molecular orbital study on the conformations of bicyclo[3.1.0]hexane derivatives.
• Chemistry of N-thiosulfinylanilines. V. Reactions of N-thiosulfinylanilines with nucleophilic reagents.
• Chemistry of N-thiosulfinylanilines. III. Thiosulfinylamine-5H-1,2,3-dithiazole equilibrium as studied by NMR spectroscopy.
• Chemistry of N-thiosulfinylanilines. II. Thermolysis and photolysis of N-thiosulfinylanilines.
• Oxidation of 4-alkyl-1-hydroxyimino-2,4,6-tri-t-butyl-2,5-cyclohexadienes. Formation of 4-alkyl-2,6-di-t-butylnitrobenzenes via iminoxyl radical.
• Reaction of 2,4,6-tri-t-butylnitrobenzene with alkyl Grignard reagents.
• Chemistry of N-thiosulfinylanilines. IV. Reactions of N-thiosulfinylanilines with electrophilic reagents.
• Chemistry of N-thiosulfinylanilines. I. Reactions of sterically hindered anilines with sulfur chlorides. Preparation of N-thiosulfinylanilines.
• Reaction of Dichlorotriphenylphosphorane with Bis(trimethylsilyl) Peroxide. A New Method for the Formation of Electrophilic Chlorine Source.
• Synthesis and reactions of o-naphthothioquinone methides.
• Revised structure of 2-cyclohexyl-3,4-diphenyl-1,2-oxaphosphetane 2-oxide.
• A new method of .ALPHA.-functionalization for tertiary amines by nucleophilic substitution of .ALPHA.-siloxy amines.
• Preparation and Thermal Decomposition of Acyl Carbamoyl Peroxides
• Synthesis and reactions of o-benzothioquinonemethides.
• Reactions of ketone hydrazones and .BETA.-keto enamines with disulfur dichloride. New synthesis of thioketones and 5H-1,2,3-dithiazoles.
• Cycloaddition reactions of thioacylketene thioacetals and N-thioacyldithioimidocarbonates.
• Phosphinidenes and Related Intermediates. III. Reactions of Phosphinylidenes and Phosphinothioylidenes with Conjugated Dienes
• Photolytic and Thermal Decompositions of 5-Substituted 1,2,3,4-Thiatriazoles in the Presence of Olefins. Reactions of Sulfur Atoms
• Synthesis and properties of o-thioquinone methides having ketene aminal, ketene acetal, ketene monothioacetal, or ketene dithioacetal group.
• Reactions of alkyl diphenylphosphinates and related thio esters with some nucleophiles. SN2 (S) reaction and Wittig type rearrangement.
• Oxidation of Diphosphine Dioxides, Disulfides and Phosphinothioite and Photolysis of Diphosphine Disulfides. Formation of Phosphinic and Phosphinothioic Anhydrides
• Reactions of thioacylketene thioacetals and o-thioquinone methides with enamines.
• Phosphinidenes and related intermediates. IV. Reactions of phosphinothioylidenes with cis- and trans-stilbene oxides.
• Metal Phosphinylides and Phosphinothioylides. IV. Reactions with Tetrahydrofuran
• Thermolysis of 6-hydroxymino-1,3,5-tri-t-butyl-5-methyl-1,3-cyclohexadiene.
• Synthesis and reactions of selenoketones.
• Reactions of 2,4,6-Tri-t-butylnitrosobenzene with Grignard Reagents

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