Metal Phosphinylides and Phosphinothioylides. IV. Reactions with Tetrahydrofuran
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概要
- 論文の詳細を見る
Diphenylphosphinic (<B>1</B>) and diphenylphosphinothioic chlorides (<B>2</B>) were allowed to react in tetrahydrofuran (THF) in the presence of metal or metal salts at 120–150°C. In the cases of lithium and magnesium, [Ph<SUB>2</SUB>PX]–(X=O, S) thus formed attacked the α-carbon of THF to give ring-opening products, which were produced by deoxygenation, sulfurization, and reaction with <B>1</B> and <B>2</B>. In the cases of iron, copper, and their salts, <I>O</I>-4-chlorobutyl diphenylphosphinate (<B>12</B>) and diphenylphosphinothioate (<B>13</B>) were obtained in a homolytic fashion. The formation mechanisms have been discussed.
- 公益社団法人 日本化学会の論文
著者
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Inamoto Naoki
Department Of Chemistry Graduate School Of Science The University Of Tokyo
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Yoshifuji Masaaki
Department Of Chemistry Faculty Of Science Tohoku University
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Okazaki Renji
Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University
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Goda Koshiro
Department of Chemistry, Faculty of Science, The University of Tokyo
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Inamoto Naoki
Department of Chemistry and Research Centre for Spectrochemistry, Faculty of Science, The University of Tokyo
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