Reactions of thioacylketene thioacetals and o-thioquinone methides with enamines.
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概要
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<I>o</I>-Thioquinone methide reacted with enamines to give [4+2] cycloadduct in good yield. In the case of morpholinoenamine, 1 : 2 adduct was obtained. Thiobenzoylketene thioacetals underwent dimerization accompanied by concomitant desulfurization upon reaction with 1-(1-pyrrolidinyl)cyclohexene. The reaction mechanism of these reactions were discussed. Some other reactions of thioacylketene thioacetals with enamines were also described.
- 公益社団法人 日本化学会の論文
著者
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Inamoto Naoki
Department Of Chemistry Graduate School Of Science The University Of Tokyo
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Okazaki Renji
Department Of Chemical And Biological Sciences Faculty Of Science Japan Women's University
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Ishii Fumio
Department of Chemistry, Faculty of Science, The University of Tokyo
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