A Grignard-type addition of allyl unit to aldehydes by using bismuth and bismuth salt.
スポンサーリンク
概要
- 論文の詳細を見る
In the presence of metallic bismuth, bismuth(III) chloride–metallic zinc, or bismuth(III) chloride–metallic iron, allylic halides have been found to react with aldehydes under mild conditions to give the corresponding homoallylic alcohols in high yields with high chemo-, regio-, and stereoselectivity. Allylic halides have been also found to react with aldehydes at room temperature in tetrahydrofuran–water by using bismuth(III) chloride–metallic aluminium to afford the expected homoallylic alcohols in high yields.
- 公益社団法人 日本化学会の論文
著者
-
Akiba Kin-ya
Department Of Chemistry Faculty Of Science Hiroshima University
-
Ohki Hidenori
Department of Chemistry, Faculty of Science, Hiroshima University
-
Wada Makoto
College of General Education, University of Tokushima
関連論文
- Synthesis of Unsymmetrically Substituted Antimony(V) Tetraphenylporphyrins
- Monomeric 10-Sb-5 Pentacoordinate Organoantimony Monohalides and Their Permutational Behavior
- Synthesis, Structure, and Reactions of 10-Sn-5 Organotin Ate Complexes
- Synthesis, Structure, and Reactions of a 10-Sb-4 Type Antimony Ate Complex
- Structure of Azabismocines, Hexacoordinate Pentavalent Organobismuth Compounds
- Synthesis and X-Ray Structures of Arsenic(V) Porphyrins with Symmetric Diaxial Ligands of Me_2 and F_2
- ^Sb Mossbauer Spectra of Hexafluorocumyl Alcohol Complexes of Sb(V), and of Sb(III) with Negative Quadrupole Coupling Contants
- Synthesis and Pseudorotational Barriers of Hypervalent Antimony Compounds Bearing Antimony-Group 6 Transition Metal Bonds
- Characterization of Enantiomeric Paris of Optically Active 10-P-5 Phosphoranes with Asymmetry Only at Phosphorus^
- Highly Z-Selective Synthesis of Disubstituted α,β-Unsaturated Cyanides and Amides Using 10-P-5 Wittig Type Reagents
- Chemistry of Nitrosoimines. VI. Attempted Syntheses of Some Resonance Stabilized Nitrosoimines and Their UV Spectra
- A Grignard-type addition of allyl unit to aldehydes by using bismuth and bismuth salt.
- Reactions of alkyl diphenylphosphinates and related thio esters with some nucleophiles. SN2 (S) reaction and Wittig type rearrangement.
- A mechanistic study on the reaction of iminothiadiazolines with activated acetylenes: Competitive pathway through hypervalent sulfurane and zwitterion.
- Chemistry of nitrosoimines. XIV. Photolysis of 5-nitrosoimino-4-phenyl-3-phenylimino-1,2,4-thiadiazolidine.
- Chemistry of Nitrosoimines. X. Reactions of 3-Substituted 2-Nitrosoimino-2,3,-dihydrobenzothiazoles with Aryl and t-Butyl Grignard Reagents
- Reactions of Diphenylphosphinothioyl Isothiocyanate and Related Compounds with Some Nucleophiles and Carbodiimides
- Alkylation of the sulfur- and nitrogen-containing compounds analogous to thiazoline systems.
- Preparation of tetraalkyl 2,2'-phthaloylbis(1,2-dihydro-1-isoquinolylphosphonate)s and their reactions with base.
- Alkylation of benzothiazolines and the Stevens rearrangement of the resulting 2,3,3-trisubstituted benzothiazolinium salts.
- A convenient method for the regioselective synthesis of 4-alkyl(aryl)pyridines using pyridinium salts.
- Equilibrium and 31P chemical shifts of the adducts of trialkylphosphines and isothiocyanates, and reactions of triethylphosphine and benzoyl isothiocyanate.
- Reaction of Alkylidenephosphoranes with Nitrosyl Chloride and Decomposition of α-Hydroxyiminophosphonium Chlorides Formed
- Chemistry of Nitrosoimines. XII. Reactions of 3-Substituted 2-Nitrosoimino-2,3-dihydrobenzothiazoles with Alkyl Grignard Reagents
- Chemistry of Nitrosoimines. XI. Reactions of 3-Substituted 2-Nitrosoimino-2,3-dihydrobenzothiazoles with Benzyl and Allylic Grignard Reagents